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Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (3): 260-263. Previous Articles     Next Articles

Original Articles

二甲亚砜-二[4,4,4-三氟-1-(2-噻吩基)-1,3-丁二酮]合铜(II)的晶体结构

李重德;游效曾;姚元根;黄锦顺;王曼芳   

  1. 南京大学配位化学研究所;中国科学院福建物质结构研究所
  • 发布日期:1987-03-15

The crystal structure of dimethylsulfoxide Bis[4,4,4-trifluoro-1-(2-thienyl)butene-1,3-dionato] copper (II)

LI ZHONGDE;YOU XIAOZENG;YAO YUANGEN;HUANG JINSHUN;WANG MANFANG   

  • Published:1987-03-15

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The title compound, C18H14CuF6O5S3, is triclinic, space group P1, with a 9.440(3), b 10.497(2), c 11.907(2) ? a 82.58(2), b 84.02(2), and g 77.93(2)? d.(calcd.) = 1.709 for Z = 2. The Cu(II) atom is coordinated with 5 O atoms, 1 of which is from Me2SO, and forms a distorted square pyramid. The thienyl groups in the ligands are cis around the Cu(II) atom.

Key words: CRYSTAL STRUCTURE DETERMINATION, X-RAY DIFFRACTION ANALYSIS, COPPER COMPLEX, DMSO, BUTANEDIONE P, ORGANO FLUORINE COMPOUNDS, THIOPHENE P, LEAST SQUARE METHODS, BETA DIKETONES

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