Synthesis and Characterization of Terpolymer Poly(propylene Cyclohexene Carbonate)s

Abstract

The terpolymerization of propylene oxide (PO) and cyclohexene oxide (CHO) with carbon dioxide (CO₂) was investigated. The IR and ¹H NMR spectra indicated that the resulting terpolymer with high molecular weight was indeed a polycarbonate. MDSC and TGA results showed that the terpolymer exhibited an extremely high glass transition temperature and decomposition temperature when compared to the copolymer from PO and CO₂. Tensile tests revealed that incorporation of CHO improved the stiffness and tensile strength of the terpolymers significantly.

Key words: carbon dioxide, terpolymerization, propylene oxide, cyclohexene oxide

Cite this article

ZOU Ying-Nan^1,2; MENG Yue-Zhong*^{,1,3. Synthesis and Characterization of Terpolymer Poly(propylene Cyclohexene Carbonate)s[J]. Acta Chimica Sinica, 2006, 64(20): 2111-2114.}

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