Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (7): 716-722. Previous Articles     Next Articles

Original Articles

雌甾-卟啉仿酶模型化合物的合成、构型与反应性

陈淑华;陈焰;李恒光   

  1. 四川大学化学系
  • 发布日期:1997-07-15

Synthesis, configuration and properties of estrogenic steroid-porphyrin enzyme model compounds

CHEN SHUHUA;CHEN YAN;LI HENGGUANG   

  • Published:1997-07-15

The model compounds of estrogenic steroid-bisporphyrins (3a) and estrogenic steroid-monoporphyrin (4a) have been synthesized by the reaction of porphyrin 1 with acyl choride of estradiol 2 followed by inserting of metal ion. The structures and configurations of 3a, 4a, and the corresponding precursors 3 and 4 were confirmed by UV-Vis, IR, 1H NMR spectra and elemental analysis. The catalytic property of 3a towards oxidation of p-benzenediol was investigated.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, PROTON MAGNETIC RESONANCE SPECTROMETRY, RESPONSIBLE, PORPHYRIN, HYDROQUINONE, OXIDATION REACTION, CATALYTIC BEHAVIOUR, CHLORACETYL CHLORIDE

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