Kinetics Study of the Synthesis of 1,3-Diamino-1,2,3-trioximinopro- pane from the Reaction of Malononitrileoxime with Hydroxylamine

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (9): 1131-1134. Previous Articles Next Articles

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2-肟基丙二腈与羟胺反应合成1,3-二氨基-1,2,3-三肟基丙烷反应动力学研究

詹祖金¹，陈小微¹，雷鸣*^,1，周彦水²，张志忠²

(¹浙江大学化学系杭州 310027)
(²西安近代化学研究所西安 710065)

投稿日期:2010-09-25 修回日期:2010-11-23 发布日期:2010-12-20
通讯作者: 雷鸣 E-mail:leiming@zju.edu.cn
基金资助:
国家重大专项基础研究项目

Kinetics Study of the Synthesis of 1,3-Diamino-1,2,3-trioximinopro- pane from the Reaction of Malononitrileoxime with Hydroxylamine

Zhan Zujin¹ Chen Xiaowei¹ Lei Ming*^,1 Zhou Yanshui² Zhang Zhizhong²

(¹Department of Chemistry, Zhejiang University, Hangzhou 310027)
(²Xi an Modern Chemistry Research Institute, Xi an 710065)

Received:2010-09-25 Revised:2010-11-23 Published:2010-12-20
Contact: Ming Lei E-mail:leiming@zju.edu.cn

The synthesis of 1,3-diamino-1,2,3-trioximinopropane from the reaction of malononitrileoxime with hydroxylamine is the key step for the preparation of furazan derivatives. The kinetics of this reaction was studied by ultraviolet absorption spectrometry. The results showed that the overall reaction was of the second-order and the order of reaction for malononitrileoxime and hydroxylamine was first-order for each. The reaction rate constant at 10 ℃ was 0.0679 L•mol^－1•min^－1. It was demonstrated that the velocity of the reaction would speed up with the increase of the malononitrileoxime concentration, the hydroxylamine concentration, and the temperature.

Key words: furazan derivatives, malononitrileoxime, 1,3-diamino-1,2,3-trioximinopropane, hydroxylamine, reaction kinetics

Cite this article

ZHAN Zu-Jin, CHEN Xiao-Wei, LEI Ming, ZHOU Yan-Shui, ZHANG Zhi-Zhong. Kinetics Study of the Synthesis of 1,3-Diamino-1,2,3-trioximinopro- pane from the Reaction of Malononitrileoxime with Hydroxylamine[J]. Acta Chimica Sinica, 2011, 69(9): 1131-1134.

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2-肟基丙二腈与羟胺反应合成1,3-二氨基-1,2,3-三肟基丙烷反应动力学研究

Kinetics Study of the Synthesis of 1,3-Diamino-1,2,3-trioximinopro- pane from the Reaction of Malononitrileoxime with Hydroxylamine

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