Fabrication of Ordered One-dimensional P3HT/CdS/TiO2/ZnO Core-Shell Nanorod Array and Their Application to Hybrid Solar Cell

doi:10.6023/A1110242

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (10): 1139-1144.DOI: 10.6023/A1110242 Next Articles

Full Papers

P3HT/CdS/TiO₂/ZnO 一维有序核壳式纳米棒阵列的构制及其在杂化太阳电池中的应用研究

郝彦忠^a, 曹寅虎^a, 孙宝^a, 张彦辉^a, 李英品^a, 徐东升^b, 李香玲^c

a 河北科技大学理学院石家庄 050018;
b 北京大学化学与分子工程学院北京 100871;
c 天津膜天膜科技股份有限公司天津 300457

投稿日期:2011-10-24 修回日期:2012-02-20 发布日期:2012-05-16
通讯作者: 郝彦忠 E-mail:yzhao@hebust.edu.cn
基金资助:
国家自然科学基金(Nos. 21173065, 20573031)、河北省自然科学基金(No. B2010000856)资助项目.

Fabrication of Ordered One-dimensional P3HT/CdS/TiO₂/ZnO Core-Shell Nanorod Array and Their Application to Hybrid Solar Cell

Hao Yanzhong^a, Cao Yinhu^a, Sun Bao^a, Zhang Yanhui^a, Li Yingpin^a, Xu Dongsheng^b, Li Xiangling^c

a College of Sciences, Hebei University of Science and Technology, Shijiazhuang 050018;
b College of Chemistry and Molecular Engineering, Peking University, Beijing 100871;
c Tianjin Motimo Membrane Tech. Co., Ltd., Tianjin 300457

Received:2011-10-24 Revised:2012-02-20 Published:2012-05-16
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21173065, 20573031) and the Natural Science Foundation of Hebei Province of China (No. B2010000856).

In this paper, ordered one-dimensional poly(3-hexylthiophene)(P3HT)/CdS/TiO₂/ZnO core-shell nanorod arrays were fabricated. Highly ordered and vertically oriented one-dimensional ZnO nanorod arrays were electrodeposited on the indium-tin oxide (ITO) glass substrates. TiO₂ sol was deposited on ZnO nanorod array by dip-coating to obtain TiO₂/ZnO core-shell nanorod array. CdS nanocrystals were electrodeposited on the TiO₂/ZnO core-shell nanorods to fabricate CdS/TiO₂/ZnO core-shell nanorod arrays. Then a thin P3HT layer was electrodeposited on the CdS/TiO₂/ZnO core-shell nanorod arrays to prepare the photoanode of the nanostructured hybrid solar cell. The photovoltaic performance of the hybrid solar cell was tested, and the mechanism of the solar cell was investigated.

Key words: TiO₂/ZnO one-dimensional core-shell nanorod arrays, CdS nanocrystals, P3HT, nanostructured hybrid solar cell

Cite this article

Hao Yanzhong, Cao Yinhu, Sun Bao, Zhang Yanhui, Li Yingpin, Xu Dongsheng, Li Xiangling. Fabrication of Ordered One-dimensional P3HT/CdS/TiO₂/ZnO Core-Shell Nanorod Array and Their Application to Hybrid Solar Cell[J]. Acta Chimica Sinica, 2012, 70(10): 1139-1144.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

1 Wang, L.; Liu, Y. S.; Jiang, X.; Qin, D. H.; Cao, Y. J. Phys. Chem. C 2007, 111, 9538.

2 Banerjee, S.; Mohapatra, S. K.; Das, P. P.; Misra, M. Chem. Mater. 2008, 20, 6784.

3 Sun, W. T.; Yu, Y.; Pan, H. Y.; Gao, X. F.; Chen, Q.; Peng, L. M. J. Am. Chem. Soc. 2008, 130, 1124.

4 Zhang, Q.-B.; Feng, Z.-F.; Han, N.-N.; Lin, L.-L.; Zhou, J.-Z.; Lin, Z.-H. Acta Phys.-Chim. Sin. 2010, 26, 2927 (in Chinese). (张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华, 物理化学学报, 2010, 26, 2927.)
5 Chen, H.; Fu, W. Y.; Yang, H. B.; Sun, P.; Zhang, Y. Y.; Wang, L. R.; Zhao, W. Y.; Zhou, X. M.; Zhao, H.; Jing, Q.; Qi, X. F.; Li, Y. X. Electrochim. Acta 2010, 56, 919.

6 Hao, Y.-Z.; Wang, W. Acta Chim. Sinica 2007, 65, 489 (in Chinese). (郝彦忠, 王伟, 化学学报, 2007, 65, 489.)
7 Gao, J. B.; Luther, J. M.; Semonin, O. E.; Ellingson, R. J.; Nozik, A. J.; Beard, M. C. Nano Lett. 2011, 11, 1002.

8 Seabold, J. A.; Shankar, K.; Wilke, R. H. T.; Paulose, M.; Varghese, O. K.; Grimes, C. A.; Choi, K. S. Chem. Mater.2008, 20, 5266.

9 Robel, I.; Subramanian, V.; Kuno, M.; Kamat, P. V. J. Am. Chem. Soc. 2006, 128, 2385.

10 Chong, L. W.; Chien, H. T.; Lee, Y. L. J. Power Sources2010, 195, 5109.

11 Jia, H. M.; Xu, H.; Hu, Y.; Tang, Y. W.; Zhang, L. Z. Electrochem. Commun. 2007, 9, 354.

12 Lee, W.; Min, S. K.; Dhas, V.; Ogale, S. B.; Han, S. H. Electrochem. Commun. 2009, 11, 103.

13 Song, X. M.; Wu, J. M.; Yan, M. Electrochem. Commun.2009, 11, 2203.

14 Wang, H.; Bai, Y. S.; Zhang, H.; Zhang, Z. H.; Li, J.; Guo, H. L. J. Phys. Chem. C 2010, 114, 16451.

15 Hao, Y.-Z.; Ma, J.-X.; Sun, B.; Li, Y.-P.; Ren, J.-J Acta Chim. Sinica 2010, 68, 33 (in Chinese). (郝彦忠, 马洁霞, 孙宝, 李英品, 任聚杰, 化学学报,2010, 68, 33.)
16 Jiang, X. X.; Chen, F.; Xu, H.; Yang, L. G.; Qiu, W. M.; Shi, M. M.; Wang, M.; Chen, H. Z. Sol. Energy Mater. Sol. Cells 2010, 94, 338.

17 Chen, H. N.; Li, W. P.; Liu, H. C.; Zhu, L. Q. Microporous Mesoporous Mater. 2011, 138, 235.

18 Plass, R.; Pelet, S.; Krueger, J.; Gr.tzel, M. J. Phys. Chem. B 2002, 106, 7578.

19 Hao, Y. Z.; Pei, J.; Wei, Y.; Cao, Y. H.; Jiao, S. H.; Zhu, F.; Li, J. J.; Xu, D. S. J. Phys. Chem. C 2010, 114, 8622.

20 Qian, D.-F.; Zhang, Q.-H.; Wan, J.; Li, Y.-G.; Wang, H.-Z. Acta Phys.-Chim. Sin. 2010, 26, 2745 (in Chinese). (钱迪峰, 张青红, 万钧, 李耀刚, 王宏志, 物理化学学报, 2010, 26, 2745.)
21 Liu, J.; Yang, H.-T.; Zhang, J.-B.; Zhou, X.-W.; Lin, Y. Acta Phys.-Chim. Sin. 2011, 27, 408 (in Chinese). (刘佳, 杨浩田, 张敬波, 周晓文, 林原, 物理化学学报,2011, 27, 408.)
22 Law, M.; Greene, L. E.; Radenovic, A.; Kuykendall, T.; Liphardt, J.; Yang, P. D. J. Phys. Chem. B 2006, 110,22652.

23 Greene, L. E.; Law, M.; Yuhas, B. D.; Yang, P. D. J. Phys. Chem. C 2007, 111, 18451.

24 Xu, L. F.; Guo, Y.; Liao, Q.; Zhang, J. P.; Xu, D. S. J. Phys. Chem. B 2005, 109, 13519.

25 Xu, L.; Chen, Q.; Xu, D. S. J. Phys. Chem. C 2007, 111,11560.

26 Qiu, J. J.; Jin, Z. G.; Liu, Z. F.; Liu, X. X.; Liu, G. Q.; Wu, W. B.; Zhang, X.; Gao, X. D. Thin Solid Films 2007, 515,2897.

27 Liao, H. C.; Chen, S. Y.; Liu, D. M. Macromolecules 2009,42, 6558.

28 Das, K.; De, S. K. J. Phys. Chem. C 2009, 113, 3494.

[1]	Cheng Pei, Shi Qinqin, Zhan Xiaowei. Ternary Blend Organic Solar Cells Based on P3HT/TT-TTPA/PC₆₁BM [J]. Acta Chim. Sinica, 2015, 73(3): 252-256.
[2]	Hao Yanzhong, Fan Longxue, Sun Bao, Sun Shuo, Pei Juan. A Photoelectrochemical Study of p-n Heterojunction between P3HT and Nanodendrite CdTe Sensitized ZnO Nanotube Array [J]. Acta Chimica Sinica, 2014, 72(1): 114-120.

P3HT/CdS/TiO₂/ZnO 一维有序核壳式纳米棒阵列的构制及其在杂化太阳电池中的应用研究

Fabrication of Ordered One-dimensional P3HT/CdS/TiO₂/ZnO Core-Shell Nanorod Array and Their Application to Hybrid Solar Cell

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 2

Recommended Articles

Metrics

Comments

P3HT/CdS/TiO2/ZnO 一维有序核壳式纳米棒阵列的构制及其在杂化太阳电池中的应用研究