Acta Chimica Sinica ›› 1979, Vol. 37 ›› Issue (1): 21-29. Previous Articles     Next Articles

四种(3,4),(8,9)-双环氧-三环[5.2.1.02,6]癸烷的合成和构型

黄志镗, 韩孝族   

  1. 中国科学院化学研究所
  • 投稿日期:1978-03-20 发布日期:2013-06-03

THE SYNTHESES AND CONFIGURATION OF FOUR(3,4),(8,9) DIEPOXYTRICYCLO-[5.2.1.02,6]DECANE ISOMERS

HUANG CHIH-TANG, HAN HSIAO-TSU   

  1. Institute of Chemistry, Academia Sinica
  • Received:1978-03-20 Published:2013-06-03

Two (8, 9)opogytricyclo[5.2.1.02,6]dec-3-enes were prepared from endoand ego-tricyclo [5.2.1.02,6] dec-3, 8-diene by partial epoxidation.Further epoxidation was carried out separately by oxidation with peracetic acid or by addition with hypoohlorite followed by elimination of hydrogen chloride.Thus four stereoisomers of (3, 4),(8, 9)diepogytrieyclo[5.2.1.02,6] decane were obtained.Their configurations were discussed.