Acta Chimica Sinica ›› 1966, Vol. 32 ›› Issue (1): 34-45. Previous Articles     Next Articles

三乙基硼的氧化及其过氧化物的热分解

陆大勋, 黃葆同, 赵晓江   

  1. 中国科学院应用化学研究所
  • 投稿日期:1965-01-09 发布日期:2013-06-03

THE AUTOXIDATION OF TRIETHYLBORON AND THE DECOMPOSITION OF ITS PEROXIDES

LU Da-Shun, HUANG Pao-Tung, CHAO Shou-Chang   

  1. Institute of Applied Chemistry, Academia Sinica
  • Received:1965-01-09 Published:2013-06-03

This work presents evidence that the autoxidation of Et3B at different temperatures gives boron peroxides which are different in their composition and decompose along distinctly different paths.Autoxidation of Et3B at 30° invariably absorbs more than one mole of oxygen per mole of Et3B (Table 1);at -70°,however,oxygen-absorption per mole of Et3B never exceeds 1.0 (Table 2).