Acta Chimica Sinica ›› 1960, Vol. 26 ›› Issue (1): 49-52. Previous Articles     Next Articles

取代氨基二硫甲酸衍生物的研究取代氨基二硫甲酸酯和次乙基-双-(氨基二硫甲酸酯)的合成

杨石先, 陈茹玉, 黎万琳, 曹惠芳, 何闵章, 胡声闻, 曹善耆   

  1. 中国科学院河北分院元素有机研究所 南开大学化学系
  • 投稿日期:1959-08-03 发布日期:2013-06-03

THE PREPARATION OF MONO- AND DI-SUBSTITUTED DITHIOCARBAMATES

YANG SHIH-HSIEN, CHEN JU-YU, LEE WAN-LING, TSAO WHEI-FON, HO MIN-CHANG, HU SHEN-WEN, TSAO SHANG-CHIE   

  1. Department of Chemistry, Nankai University, Research Institute of Elemental Organic Chemistry, Hopei Branch of Academia Sinica, Tientsin
  • Received:1959-08-03 Published:2013-06-03

(1) By the reaction of a mixture of an amine hydrochloride,carbon disulfide,and aqueous sodium hydroxide directly with a halide,series of esters of mono- and disubstituted dithiocarbaniic acid was prepared.(2) Some ethylene bis-dithiocarbamic esters were prepared by allowing the disodium ethylem bis-dithiocarbatnates to react separately with 3-chloroallyl chloride, 2-chloroallyl chloride,β-bromopropionic acid.The physical constants and yields of the compounds mentioned are tabulated in Table 1 (with English) of the Chinese text(p.51).