Synthesis and Up-Converted Fluorescence of D-π-A Compounds with N and B as the Centers of Electron Donating and Accepting Groups

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (20): 2103-2108. Previous Articles Next Articles

氮硼为电子授受中心的D-π-A化合物的合成与上转换荧光

刘志强^1,2, 曹笃霞¹, 方奇^1,2, 刘国群¹, 许贵宝¹

1. 山东大学晶体材料国家重点实验室, 济南, 250100;
2. 山东大学化学与化工学院, 济南, 250100

投稿日期:2004-02-01 修回日期:2004-04-06 发布日期:2014-02-17
通讯作者: 方奇,E-mail:fangqi@icm.sdu.edu.cn E-mail:fangqi@icm.sdu.edu.cn
基金资助:
国家自然科学基金(No.20172034)和高等学校骨干教师计划资助项目.

Synthesis and Up-Converted Fluorescence of D-π-A Compounds with N and B as the Centers of Electron Donating and Accepting Groups

LIU Zhi-Qiang^1,2, CAO Du-Xia¹, FANG Qi^1,2, LIU Guo-Qun¹, XU Gui-Bao¹

1. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100

Received:2004-02-01 Revised:2004-04-06 Published:2014-02-17

Abstract

Two novel fluorene derivatives with dimesitylboryl as electron acceptor and diphenylamino or carbazolyl as electron donor have been synthesized, which are named 2-(N,N-diphenylamino)-7-dimesitylboryl-9,9-diethyl-fluo~rene (1) and 2-carbazolyl-7-dimesitylboryl-9,9-diethylfluorene (2). Upon excitation by femtosecond laser with a pulse-width of 200 fs, both compounds exhibit strong blue two-photon excited fluorescence in THF with λ_max=484 nm for 1 and λ_max=440 nm for 2. Their two-photon absorption cross-sections obtained by two-photon fluorescence method are 425 GM (1, excited at 800 nm) and 116 GM (2, excited at 730 nm).

Key words: dimesitylboryl, fluorene derivative, two-photon absorption, up-converted fluorescence

Cite this article

LIU Zhi-Qiang, CAO Du-Xia, FANG Qi, LIU Guo-Qun, XU Gui-Bao. Synthesis and Up-Converted Fluorescence of D-π-A Compounds with N and B as the Centers of Electron Donating and Accepting Groups[J]. Acta Chimica Sinica, 2004, 62(20): 2103-2108.

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氮硼为电子授受中心的D-π-A化合物的合成与上转换荧光

Synthesis and Up-Converted Fluorescence of D-π-A Compounds with N and B as the Centers of Electron Donating and Accepting Groups

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