Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (12): 2636-2641.DOI: 10.6023/cjoc201506018 Previous Articles     Next Articles



欧阳跃军a,b, 邱仁华b, 陈四海b, 陈锦杨b, 许新华b   

  1. a 怀化学院化学与化学工程系 怀化 428000;
    b 湖南大学化学化工学院 长沙 410082
  • 收稿日期:2015-06-15 修回日期:2015-08-05 发布日期:2015-08-26
  • 通讯作者: 许新华
  • 基金资助:

    国家自然科学基金(Nos. 21273068, 21172061)、湖南省科技计划(No. 2013FJ3023)资助项目.

KOH-Catalyzed Synthesis of O,O-Dialkyl-S-aryl Phosphoroselenoates Activated by Novel Calix[4]arene

Ouyang Yuejuna,b, Qiu Renhuab, Chen Sihaib, Chen Jinyangb, Xu Xinxub   

  1. a Department of Chemistry and Chemical Engineering, Huaihua University, Huaihua 418000;
    b College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082
  • Received:2015-06-15 Revised:2015-08-05 Published:2015-08-26
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21273068, 21172061), the Planned Science and Technology Project of Hunan Province (No. 2013FJ3023).

A novel calix[4]arene 3 was synthesized. The experimental results show that the reactions of O,O-dialkylphos- phonates and diaryl(alkyl) disulfides proceed efficiently in the presence of calix[4]arene 3 (5.0 mol%) and KOH (20 mol%), affording O,O-dialkyl-S-aryl(alkyl)phosphoroselenoates in good to excellent yields. The yields of desired products do not reduce after recycling for 6 times of calix[4]arene 3. Hence, a convenient and efficient method for the preparation of O,O-dial- kyl-S-aryl(alkyl)phosphoroselenoates was provided, avoiding the use of some foul and toxic reagents.

Key words: novel calix[4]arene, diaryl(alkyl) disulfide, O,O-dialkylphosphonate, O,O-dialkyl-S-aryl(alkyl)phosphoro-selenoate