Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (6): 1577-1581.DOI: 10.6023/cjoc201701016 Previous Articles     Next Articles

Notes

阿拉华蜡孔菌中四个新的2,5-二取代呋喃邻二醇(英文)

刘良燕a, 冯涛b, 李正辉b, 刘吉开b   

  1. a. 云南农业大学农学与生物技术学院 昆明 650201;
    b. 中南民族大学药学院 武汉 430074
  • 收稿日期:2017-01-07 修回日期:2017-01-20 出版日期:2017-06-25 发布日期:2017-01-20
  • 通讯作者: 刘吉开 E-mail:jkliu@mail.kib.ac.cn
  • 基金资助:

    Project supported by the National Natural Science Foundation of China (Nos. 21502167, 81561148013).

Four New 2,5-Disubstituted Furan Vicinal Diols from the Fungus Ceriporia alachuana

Liu Liangyana, Feng Taob, Li Zhenghuib, Liu Jikaib   

  1. a. College of Agronomy and Biotechnology, Yunnan Agricultural University, Kunming 650201;
    b. School of Pharmaceutical Sciences, South-Central University for Nationalities, Wuhan 430074
  • Received:2017-01-07 Revised:2017-01-20 Online:2017-06-25 Published:2017-01-20
  • Contact: 10.6023/cjoc201701016 E-mail:jkliu@mail.kib.ac.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21502167, 81561148013).

Four new closely related vicinal diols, (1R,2R)-1-(5-(pent-4-en-1-yl)furan-2-yl)propane-1,2-diol (1), (1S,2R)-1-(5-(pent-4-en-1-yl)furan-2-yl)propane-1,2-diol (2), (1R,2R)-1-(5-pentylfuran-2-yl)propane-1,2-diol (3) and (1R,2S)-1-(5-pen-tylfuran-2-yl)propane-1,2-diol (4), were isolated from the cultures of the fungus Ceriporia alachuana. Their structures and absolute configurations were totally determined by spectroscopic means, chemical method (forming di-O-isopropylidene derivative) and Mo2(OAc)4 induced circular dichroism (ICD) experiments.

Key words: vicinal diols, Ceriporia alachuana, induced circular dichroism (ICD), dimolybdenum tetraacetate