Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (10): 2745-2751.DOI: 10.6023/cjoc201704001 Previous Articles     Next Articles



黄昱霖a, 陈迁a,b   

  1. a 广东工业大学轻工化工学院 广州 510006;
    b 华南理工大学 广东省功能分子工程重点实验室 广州 510640
  • 收稿日期:2017-04-01 修回日期:2017-05-10 发布日期:2017-06-02
  • 通讯作者: 陈迁
  • 基金资助:


Fluorination Reaction of P(Ⅲ) Compounds with the Electrophilic Fluorinating Reagent Selectfluor

Huang Yulina, Chen Qiana,b   

  1. a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006;
    b Key Laboratory of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510640
  • Received:2017-04-01 Revised:2017-05-10 Published:2017-06-02
  • Contact: 10.6023/cjoc201704001
  • Supported by:

    Project supported by the Science and Technology Planning Project of Guangdong Province (No.2015A020211026),the 100 Young Talents Program of Guangdong University of Technology (No.220413506) and the Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province (No.2016kf07).

A fluorination reaction of P(Ⅲ) compounds with the electrophilic fluorinating reagent Selectfluor is described. The reaction proceeded in acetonitrile/water at room temperature for 15~60 min to afford phosphoric fluorides in 34%~81% yields.

Key words: P(Ⅲ) compound, electrophilic fluorinating reagent, fluorination reaction, phosphoric fluoride