Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (1): 272-276.DOI: 10.6023/cjoc201708059 Previous Articles     Next Articles

Special Issue: 庆祝吴养洁院士九十华诞专辑 碳氢活化合辑2018-2019 有机硅化学合辑

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金(I)催化的萘环上三甲基硅基的1,2-迁移反应

杨琪, 刘亮, 张文雄, 席振峰   

  1. 北京大学化学学院 北京 100871
  • 收稿日期:2017-08-29 修回日期:2017-09-19 发布日期:2017-09-19
  • 通讯作者: 席振峰 E-mail:zfxi@pku.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21372012,21690061)资助项目.

Gold(I)-Catalyzed 1, 2-Migration of a SiMe3 Group on Naphthalene Rings

Yang Qi, Liu Liang, Zhang Wen-Xiong, Xi Zhenfeng   

  1. College of Chemistry, Peking University, Beijing 100871
  • Received:2017-08-29 Revised:2017-09-19 Published:2017-09-19
  • Contact: 10.6023/cjoc201708059 E-mail:zfxi@pku.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21372012, 21690061).

A gold(I)-catalyzed 1,2-silyl migration on 1,8-di-substituted naphthalene rings was realized by synergistic effect of Lewis acid and water. High yields were achieved under relatively mild conditions.

Key words: gold(I)-catalysis, 1,2-silyl migration, 1,8-di-substituted naphthalene ring