Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (5): 1085-1106.DOI: 10.6023/cjoc201709014 Previous Articles     Next Articles

Reviews

染料敏化太阳电池:染料中稳定锚基团的研究进展

田亚娟a, 蔡宁a, 陈亚通a, 钱赛男a, 霍延平a,b   

  1. a 广东工业大学轻工化工学院 广州 510006;
    b 中国科学院上海有机化学研究所 有机氟化学中国科学院重点实验室 上海 200032
  • 收稿日期:2017-09-08 修回日期:2017-11-16 出版日期:2018-05-25 发布日期:2017-12-08
  • 通讯作者: 蔡宁,E-mail:ning.cai@gdut.edu.cn;霍延平,E-mail:organicteacherhuo@126.com E-mail:ning.cai@gdut.edu.cn;organicteacherhuo@126.com
  • 基金资助:

    广东省自然科学基金(No.2017A030310039)、国家自然科学基金(Nos.61671162,21372051)、广东省科技计划(No.2016A010103031)资助项目.

Dye-Sensitized Solar Cells: Progress on Robust Anchor Groups in Dyes

Tian Yajuana, Cai Ninga, Chen Yatonga, Qian Sainana, Huo Yanpinga,b   

  1. a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006;
    b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Cheimstry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2017-09-08 Revised:2017-11-16 Online:2018-05-25 Published:2017-12-08
  • Contact: 10.6023/cjoc201709014 E-mail:ning.cai@gdut.edu.cn;organicteacherhuo@126.com
  • Supported by:

    Project supported by the Natural Science Foundation of Guangdong Province (No. 2017A030310039), the National Natural Science Foundation of China (Nos. 61671162, 21372051) and the Science and Technology Planning Project of Guangdong Province (No. 2016A010103031).

As a type of potential photovoltaic device, dye-sensitized solar cells (DSSCs) have attracted tremendous attention due to its high cost-effective and simple manufacturing process. In the device, dye molecules attach on the metal oxide surface via chemical bonds between anchor substituents and metal oxide substrate, realizing the light harvesting and photoelectron injection. Traditionally, carboxylic acids, such as benzoic acid and cyanoacrylic acid groups, have been widely utilized as the anchor groups in DSSCs. However, the detachment of dye molecules from metal oxide surface during device operation and consequent long-term stability issues cannot be ignored. Therefore, in view of durability of DSSCs in practical application, various anchor groups with a better ability to graft on the metal oxide have been explored. Several robust anchor groups in recent years and corresponding photovoltaic parameters are reviewed and the relationship between molecular structures and device performance is also discussed. The research progress of anchoring groups in photocatalytic hydrogen and quantum dot sensitized solar cells (QDSSCs) is also examined.

Key words: dye-sensitized solar cell, dye sensitizer, anchor group, stability