Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 2045-2053.DOI: 10.6023/cjoc201802003 Previous Articles     Next Articles

Special Issue: 元素有机化学合辑2018-2019



李志娟, 翦辉, 王伟华, 王强, 何林   

  1. 石河子大学化学化工学院 石河子 832000
  • 收稿日期:2018-02-02 修回日期:2018-04-23 发布日期:2018-05-03
  • 通讯作者: 何林
  • 基金资助:


Insertion Reaction of Benzynes and Stable Sulfur Ylide

Li Zhijuan, Jian Hui, Wang Weihua, Wang Qiang, He Lin   

  1. School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000
  • Received:2018-02-02 Revised:2018-04-23 Published:2018-05-03
  • Contact: 10.6023/cjoc201802003
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21462034).

Benzynes undergo insertion reaction with C=S bond of the stable sulfur ylide through a cascade[2+2] cycloaddition and ring-opening reaction to construct a new C-S bond, producing ortho-substituted aryl-alkyl thioether derivatives in moderate to good yields.

Key words: benzyne, sulfur ylide, insertion reaction, C-S bond