Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (4): 1085-1094.DOI: 10.6023/cjoc201809042 Previous Articles     Next Articles

Articles

色烯并[4,3-d]吡唑并[3,4-b]吡啶衍生物的三组分合成及荧光性质研究

张梦烨, 王宁, 徐文韬, 黄志斌, 史达清   

  1. 苏州大学材料与化学化工学部 江苏省有机合成重点实验室 苏州 215123
  • 收稿日期:2018-09-29 修回日期:2018-12-10 出版日期:2019-04-25 发布日期:2018-12-21
  • 通讯作者: 黄志斌, 史达清 E-mail:dqshi@suda.edu.cn;zbhuang@suda.edu.cn
  • 基金资助:

    江苏省高校自然科学重大研究(Nos.15KJA150006,17KJA150006)资助项目.

Three-Component Synthesis of Chromeno[4,3-d]pyrazolo[3,4-b]-pyridine Derivatives and Their Fluorescence Properties

Zhang Mengye, Wang Ning, Xu Wentao, Huang Zhibin, Shi Daqing   

  1. College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, Suzhou 215123
  • Received:2018-09-29 Revised:2018-12-10 Online:2019-04-25 Published:2018-12-21
  • Contact: 10.6023/cjoc201809042 E-mail:dqshi@suda.edu.cn;zbhuang@suda.edu.cn
  • Supported by:

    Project supported by the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (Nos.15KJA150006,17KJA150006).

A series of 5-aminochromeno[4,3-d]pyrazolo[3,4-b]pyridin-6(3H)-one derivatives 4a~4w were synthesized by three-component reactions of salicylaldehydes, ethyl cyanoacetate and 5-aminopyrazoles catalyzed by triethylamine (TEA). The properties of the synthesized compounds were examined by fluorescence spectroscopy and the results indicated that some compounds were possessed high fluorescence quantum yields.

Key words: chromeno[4,3-d]pyrazolo[3,4-b]pyridine, three-component synthesis, fluorescence property