NMR spectra of alkyl dialkoxyphosphinylacetates

Chin. J. Org. Chem. ›› 1988, Vol. 8 ›› Issue (6): 545-549. Previous Articles Next Articles

二烷氧基膦酰乙酸酯的核磁共振

史丽萍;陈朝环;叶伟贞;廖秀高

中国科学院上海有机化学研究所

发布日期:1988-12-25

NMR spectra of alkyl dialkoxyphosphinylacetates

SHI LIPING;CHEN CHAOHUAN;YE WEIZHEN;LIA XIUGAO

Published:1988-12-25

Abstract

The structure of (RO)2P(O)CH2CO2R1 (R = alkyl; R1 = alkyl, cycloalkyl) were determine by means of 1H, 31P and 13C NMR. The chem. shifts and JHP, 2JCCPand 3JCCOPare reported. With the change of temperature, the hindered rotating of P-O-C bonds was observed

Key words: ACETIC ACID ESTER, ALKOXYL GROUP, PHOSPHONIC ACID ESTER, COUPLING CONSTANT, CHEMICAL SHIFT, NUCLEAR MAGNETIC RESONANCE

CLC Number:

O627

Cite this article

SHI LIPING;CHEN CHAOHUAN;YE WEIZHEN;LIA XIUGAO. NMR spectra of alkyl dialkoxyphosphinylacetates[J]. Chin. J. Org. Chem., 1988, 8(6): 545-549.

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二烷氧基膦酰乙酸酯的核磁共振

NMR spectra of alkyl dialkoxyphosphinylacetates

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