Studies on reaction of iron carbonyls-thiophenol-triethylamine system: Synthesis and characterization of (μ-acyl)(μ-phenylthio) and ( μ-σ,π-alkenyl)(μ-phenylthio) hexacarbonyldiiron

Chin. J. Org. Chem. ›› 1989, Vol. 9 ›› Issue (1): 51-54. Previous Articles Next Articles

羰基铁-硫酚-三乙胺反应体系的研究:(μ-酰基)(μ-苯硫)及(μ-σ,π-烯基)(μ-苯硫)六羰基二铁配合物的合成

宋礼成;刘金亭;王积涛

南开大学化学系

发布日期:1989-02-25

Studies on reaction of iron carbonyls-thiophenol-triethylamine system: Synthesis and characterization of (μ-acyl)(μ-phenylthio) and ( μ-σ,π-alkenyl)(μ-phenylthio) hexacarbonyldiiron

SONG LICHENG;LIU JINTING;WANG JITAO

Published:1989-02-25

Abstract

[Et3NH][Fe2(CO)6(m-CO)(m-PhS)], which was formed from Fe3(CO)12, PhSH and Et3N, reacts with ArCOCl (Ar = Ph, a = naphthyl), RCH:CR1COCl (R = Me, Ph, H; R1 = H, Me) or R2COCH:CHCl (R2 = Ph, p-tolyl) to form Fe2(CO)6(m-PhS)L (L = m-acyl, m-s,p-alkenyl). The complexes were characterized by IR and 1H NMR spectroscopy.

Key words: IRON COMPLEX, CARBONYL COMPLEX, THIOPHENOLS, BRIDGE COMPOUNDS, TRIETHYL AMINE, AKENE COMPLEX

CLC Number:

O627

Cite this article

SONG LICHENG;LIU JINTING;WANG JITAO. Studies on reaction of iron carbonyls-thiophenol-triethylamine system: Synthesis and characterization of (μ-acyl)(μ-phenylthio) and ( μ-σ,π-alkenyl)(μ-phenylthio) hexacarbonyldiiron[J]. Chin. J. Org. Chem., 1989, 9(1): 51-54.

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羰基铁-硫酚-三乙胺反应体系的研究:(μ-酰基)(μ-苯硫)及(μ-σ,π-烯基)(μ-苯硫)六羰基二铁配合物的合成

Studies on reaction of iron carbonyls-thiophenol-triethylamine system: Synthesis and characterization of (μ-acyl)(μ-phenylthio) and ( μ-σ,π-alkenyl)(μ-phenylthio) hexacarbonyldiiron

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