Chin. J. Org. Chem. ›› 1994, Vol. 14 ›› Issue (2): 153-158. Previous Articles     Next Articles

Original Articles

1-烷基-4,6-二芳基四氢三嗪硫酮化合物的合成及其氧化反应

任平达;贾韵仪;董庭威   

  1. 复旦大学化学系
  • 发布日期:1994-04-25

Synthesis and oxidation of 1-alkyl-4,6-diaryl- tetrahydro-S-triazine-2(1H)-thiones

Ren Pingda;JIA YUNYI;DONG TINGWEI   

  • Published:1994-04-25

1-alkyl-4,6-diaryl-tetrahydro-S-triazine- 2(1H)-thiones 3 were prepared by reactions of N,N'-diarylmethylenearylmethanediamines with alkylthioureas, or by mixing arylaldehyde. alkylthioureas and ammonium acetate in one pot process. Amarinethiocynate was obtained by reactions of N,N'-diarylmethylenearylme- thanediamines with arylthioureas. 3 have been oxidized to 1-alkyl-4,6-diaryl-S-triazine-2(1H)- ones by potassium permanganate in the presence of TEBA at room temperature.

Key words: TRIAZONE, OXIDATION REACTION

CLC Number: