The reactions of N-trimethylsilyl-p-toluenesulfonamide  with tosylates

Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (5): 478-480. Previous Articles Next Articles

Original Articles

N-三甲基硅基对甲苯磺酰胺与对甲苯磺酸酯的反应

荣国斌;王Bing;马汝建

华东理工大学化学系.上海(200237);中国科学院上海有机化学研究所.上海 (200032)

发布日期:1998-10-25

The reactions of N-trimethylsilyl-p-toluenesulfonamide with tosylates

Rong Guobin;WANG Bi;Ma Rujian

East China Univ of Sci Tech., Dept Chem.Shanghai(200237);Shanghai Inst Organ Chem., CAS.Shanghai(200032)

Published:1998-10-25

Abstract

N-p-Tosyl-mopholine or N-p-tosyl-tetrahydropyrrole and N-methyl- p- toluenesulfonamide were prepared by the reactions of N- trimethylsilyl- p-toluenesulfonamide with 3-oxa-1, 5-pentadiol ditosylate or 1, 4- butadiol ditosylate and methyl p-tosylate respectively. The possible pathway was suggested.

Key words: TRANSITION STATE, ALKYLSULFONATE, P-METHYLBENZENESULFONIC ACID P, REACTION PATH, SULFONYL GROUP, P-METHYLBENZENESULFONIC ACID P, SIX MEMBER RING HETEROCYCLICS COMPOUNDS, TRIMETHYLSIL ANES, BENZENESULFONAMIDE P, P-METHYLBENZENESULFONIC ACID P

CLC Number:

O627

Cite this article

Rong Guobin;WANG Bi;Ma Rujian. The reactions of N-trimethylsilyl-p-toluenesulfonamide with tosylates[J]. Chin. J. Org. Chem., 1998, 18(5): 478-480.

[1]	Jingpeng Li, Shuntao Huang, Qi Yang, Weiqiang Li, Teng Liu, Chao Huang. A Practical Synthesis of (Z)-N-Vinyl Substituted N,O-Acetals under Continuous Flow Technology [J]. Chinese Journal of Organic Chemistry, 2023, 43(4): 1550-1558.
[2]	Kairui Zhang, Yaya Wang, Hongdan Zhu, Qian Peng. Advances on Quasi-classical Molecular Dynamics of Organic Reaction Mechanisms [J]. Chinese Journal of Organic Chemistry, 2021, 41(10): 3995-4006.
[3]	CHU Wen-Hai, GAO Ai-Yun, DENG Yang-. Stability of Newfound Nitrogenous Disinfection By-products Haloacetamides in Drinking Water [J]. Chin. J. Org. Chem., 2009, 29(10): 1569-1574.
[4]	Yang Siya;Sun Chengke;Lin Xuefei. Theoretical Study on the Influence of Substituents on Enantioselecthity in Branched-Oxazaborolidine-Catalyzed Reductions of Phenyl-ethyl Ketone [J]. Chin. J. Org. Chem., 2003, 23(12): 1400-1406.
[5]	Xu Jiaxi. Synthesis of Hydroxyalkanesulfonic Acids,Aminoalkanesulfonic Acids and Sulfonopeptides [J]. Chin. J. Org. Chem., 2003, 23(1): 1-9.
[6]	Luo Yunfu;Li Yuanchao. Asymmetric synthesis of chiral vicinal diol (2s,3r)-1,2,3- butanetriol-1-p-methylbenzensulfonate [J]. Chin. J. Org. Chem., 2002, 22(4): 262-264.
[7]	Sun Li;Pei Wen. Asymmetric diels-alder reactions of (E)-1-phenylsulfonyl-3-penten -2-one with open ring diene catalyzed by a chiral titanium reagent [J]. Chin. J. Org. Chem., 2002, 22(11): 922-925.
[8]	Zhao Weiguang;Li Zhengming;Yuan Pingwei;Yuan Dekai;Jia Qiang;Wang Wenyan;Wang Suhua. Synthesis and biological activity of 3-methyl-4- ethoxyl (diethylamino)carbonyl-1H-pyrazole derivatives [J]. Chin. J. Org. Chem., 2001, 21(8): 593-598.
[9]	Sha Yaowu;Wang Yu;Ge Jun;Wang Xin. Application of microwave irradiation in the synthesis of heterocyclic compounds [J]. Chin. J. Org. Chem., 2001, 21(2): 102-115.
[10]	Zhu Shizheng;Xu Yong;Wang Yanli. Recent developments in the research of reactions of fluoroalkanesulfonyl azides [J]. Chin. J. Org. Chem., 2001, 21(11): 986-992.
[11]	Xue Sijia;Wang Tao;Liao Zhanru. Synthesis of N'-4,5,6trisubstituted-2-pyrimidin-yl-N-2- sulfonylbenzoyl-imino acetylureas [J]. Chin. J. Org. Chem., 2000, 20(5): 731-734.
[12]	Yang Nianfa;Yang Liwen;Lin Yongcheng;Zeng Longmei. The enantioselective catalysis of the complexes of titanium with sulfonylamino acids in the Diels-Alder reaction [J]. Chin. J. Org. Chem., 2000, 20(3): 395-397.
[13]	Nie Xiaoping;Ye Xiulin. Conformational effect in some organic reactions [J]. Chin. J. Org. Chem., 1999, 19(2): 109-120.
[14]	Kang Ruhong;Wu Ruitao;Zhen Xiaoli. A preparation of hydrocarbyl sulfuryl chloride by the oxidation of sulfocompounds [J]. Chin. J. Org. Chem., 1998, 18(6): 559-561.
[15]	XU CUILIAN;CHEN ZHENCHU;YANG YUFENG. Synthesis of 5-alkyl-5-tosyloxyl-isopropylidene malonate [J]. Chin. J. Org. Chem., 1997, 17(5): 474-477.

N-三甲基硅基对甲苯磺酰胺与对甲苯磺酸酯的反应

The reactions of N-trimethylsilyl-p-toluenesulfonamide with tosylates

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments