Study on synthesis of the sex pheromone of peach  leafminer moth

Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (5): 528-532. Previous Articles Next Articles

Original Articles

桃潜蛾性信息素的合成研究

黄锦霞;李焰;马兴泉;周忠强

湖北大学化学与材料科学学院

发布日期:1999-10-25

Study on synthesis of the sex pheromone of peach leafminer moth

Huang Jinxia;Li Yan;Ma Xingquan;Zhou Zhongqiang

Published:1999-10-25

Abstract

Grignard agents (n-C~4H~9MgBr) in the presence of CuBr.Me~2S underwent 1, 4-Michael addition to N-crotonoyl-bornanesultam prepared from D-(-)-bornanesultam and crotonoic anhydride to give the main product of S-configuration. The sex pheromone of peach leafminer moth-(S)-14-methyl-1-octadecene 1 and its enantiomer (R)-1 were prepared via six steps of readions with the optical purity being 97% and 95%, respectively.

Key words: BORNANE, SULFAMIDE P, LACTAM P, SEX PHEROMONE

CLC Number:

O629

Cite this article

Huang Jinxia;Li Yan;Ma Xingquan;Zhou Zhongqiang. Study on synthesis of the sex pheromone of peach leafminer moth[J]. Chin. J. Org. Chem., 1999, 19(5): 528-532.

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桃潜蛾性信息素的合成研究

Study on synthesis of the sex pheromone of peach leafminer moth

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