Chin. J. Org. Chem. ›› 2001, Vol. 21 ›› Issue (11): 805-809. Previous Articles     Next Articles

抑铬雾剂F-53的研制带动了有机氟化学的发展

陈庆云   

  1. 中国科学院上海有机化学研究所有机氟化学实验室
  • 发布日期:2001-11-25

Some progress in organofluorine chemistry promoted by the preparation of chromic acid mist suppressant, F-53

Chen Qingyun   

  • Published:2001-11-25

This review includes the synthesis of perfluoroalkane- sulfonic esters, single electrom-transfer reactions of perfluoroalkyl iodides, difluorocarbene precursors and trifluoromethylation of organic halides. All these reactions are derived from the preparation of chromic acid mist suppressant F-53, CF3(CF2)5OCF2CF2SO3K.

Key words: ORGANO FLUORINE COMPOUNDS, SINGLE ELECTRON TRANSFER REACTION, PERFLUORO-HYDROCARBON, SULFONIC ACID ESTER, CHROMIUM PLATING, CHROMIC ACID

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