Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (7): 717-719. Previous Articles     Next Articles

手性1-β-羧乙基杂氮锗三环类化合物的合成

陶春元;吕群;帅敏   

  1. 九江师范专科学校
  • 发布日期:2003-07-25

Synthesis of Chiral 1-β-Carboxyethylgermatranes

Tao Chunyuan;Lu Qun;Shuai Min   

  1. Jiujiang Teacher's College
  • Published:2003-07-25

(4S)-l-/?-carboxyethyl-4-carboxylgermatrane (1). (4S )-3-methyl-l- ^-carboxyethyl-4-carboxylgerma-trane (2) and (4S)-l-/3-carboxyethyl-4- carboxyl-2-thiogermatrane (3) were synthesized by solid-state reaction of several L-N, Af-bis(/3-hydroxyethyl) amino-acids with /3- tricHorogermapropanic acid and characterized by elemental analysis, IR, JH NMR and MS spectra.

Key words: SOLID PHASE REACTION;ORGANO GERMANIUM;NITROGEN HETEROCYCLICS;CARBOXY GROUP, SULFUR COMPOUNDS;ELEMENTAL ANALYSIS;1HNMR;MS;STRUCTURE CHARACTERISTICS

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