A Novel Reaction of (CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb) with Cyclopentadiene Forming (C_5H_5)_3Ln·THF

Chin. J. Org. Chem. ›› 2003, Vol. 23 ›› Issue (9): 1029-1032. Previous Articles Next Articles

(CH_3C_5H_4)_3Ln·THF(Ln=Sm,Ho,Tb,Yb)与环戊二烯生成(C_5H_5)_3Ln·THF的新反应

刘太奇;丁福臣;林永华;于建香;师奇松;沈琪

北京石油化工学院材料与化工系;中国科学院长春应用化学研究所;苏州大学化学系

发布日期:2003-09-25

A Novel Reaction of (CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb) with Cyclopentadiene Forming (C_5H_5)_3Ln·THF

Liu Taiqi;Ding Fuchen;Lin Yonghua;Yu Jianxiang;Shi Qisong;Shen Qi

School of Materials and Chemical Engineering, Beijing Institute of Petro-chemical Technology;Changshun Institute of Applied Chemistry, Chinese Academy of Sciences;Department of Chemistry, Suzhou University

Published:2003-09-25

Abstract

A novel reaction of(CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb)with cyclopentadiene obtained (C_5H_5)_3Ln·THF in high yield. The products were characterized by elemental analyses, MS and X-ray diffraction analysis. The data of selected structure parameters of (C_5H_5)_3Ln· THF, such as the average distance between the penta carbon ring and the central metal, the distance between the penta carbon center or the coordinated THF and the central metal, showed that their values decreased with the increase of atomic number. It suggests that these compounds obey the "lanthanide contract" rule.

Key words: CYCLOPENTADIENE;SAMARIUM COMPLEX;HOLMIUM COMPLEX;TERBIUM COMPLEX, YTTERBIUM COMPLEX;ELEMENTAL ANALYSIS;MS;XRD;FURAN P

CLC Number:

O621

Cite this article

Liu Taiqi;Ding Fuchen;Lin Yonghua;Yu Jianxiang;Shi Qisong;Shen Qi. A Novel Reaction of (CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb) with Cyclopentadiene Forming (C_5H_5)_3Ln·THF[J]. Chin. J. Org. Chem., 2003, 23(9): 1029-1032.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	MA Cha, LI Long, SUN Jin-Sheng, ZHAO Feng, LI Yi-Long. Recent Progress in Dansyl-Based Dendrimers [J]. Chin. J. Org. Chem., 2011, 31(12): 1977-1988.
[2]	LIU Bin, XIE Long-Guan, XU Xiao-Hua, LI Yong-Hong. Synthesis, Crystal Structure and Herbicidal Activity of 3-Benzoyl-4-hydroxycoumarin Derivatives [J]. Chin. J. Org. Chem., 2011, 31(12): 2067-2073.
[3]	WANG Gang-Qiang, CHEN Yu-Ling, HAN Ming-Song, SUN Liang, WANG Qiu-An. Synthesis and Biological Activity of Pterostilbene and 3-Methoxy Pterostilbene and Their Glucosides Derivatives [J]. Chin. J. Org. Chem., 2011, 31(12): 2114-2120.
[4]	ZHANG Hua-Cheng, LIU Zhao-Na, XIN Fei-Fei, LI Yue-Ming, KONG Li, HAO Ai-You. Atom Transfer Radical Polymerization Based on Cyclodextrin [J]. Chin. J. Org. Chem., 2011, 31(11): 1761-1772.
[5]	ZHANG Huan, LI Hai-Gang, WU Hai-Hong. Synthesis of Chiral Imidazolinone-Based Ionic Liquids [J]. Chin. J. Org. Chem., 2011, 31(9): 1433-1439.
[6]	. Synthesis and Antitumor Activity of 5,6-2H-[1,2,4]- triazolo [3,4-b][1,3,4]thiadiazine derivatives [J]. Chin. J. Org. Chem., 2011, 31(06): 912-920.
[7]	YI Bing, ZHANG Yang, SHU Xiao-Ma, YANG Yan, DU Wen-Le, LIU Zhan-Peng. Study on Henry Reaction Catalyzed by Dendritic Amines [J]. Chin. J. Org. Chem., 2011, 31(06): 874-877.
[8]	WEI Ben-Mei, ZHANG Zhi-Yong, DAI Zhi-Qun, ZHANG Kai-Cheng. Friedel-Crafts Benzylation of Aromatic Compounds Catalyzed by Chloroapatite Supported Metal Halides [J]. Chin. J. Org. Chem., 2011, 31(03): 392-396.
[9]	LIU Zhi-Chang, LIU Xiao-Xia, WANG Ying-Hong, YANG Lu. Synthesis and Biological Activities of N-Coumarin-3-formacyl-N - substitute Thioreas De-rivatives [J]. Chin. J. Org. Chem., 2011, 31(01): 136-140.
[10]	FAN Wen-Ming, GAO Jian-Rong, JIA Jian-Hong, HAN Liang, SHENG Wei-Jian, LI Yu-Jin. Solvent-Free Synthesis of β-Enamino Ketones (Esters) under High-Speed Vibration Miling (HSVM) Condition [J]. Chin. J. Org. Chem., 2010, 30(11): 1732-1736.
[11]	WANG Chao, ZHENG Xue-Fang, ZHANG Qian, LIU Qun. Progress in the Study of Different Position Substituted Thia-zolidine-4-carboxylic Acid and Its Derivatives [J]. Chin. J. Org. Chem., 2010, 30(10): 1441-1454.
[12]	XIONG Wen-Shuo, WANG Hong, YI Yu, MEI Jian-Feng, YING Guo-Qing. Progress of Crystallization-Induced Asymmetric Transformation in Resolution of Chiral Compounds [J]. Chin. J. Org. Chem., 2010, 30(07): 951-957.
[13]	YANG Xu-Hong, WU Ming-Hu, DING Ming-Wu. Synthesis of 2,2 -Disubstituted Bis(3-arylquinazolin-4(3H)-one)s [J]. Chin. J. Org. Chem., 2010, 30(07): 1032-1038.
[14]	LIU Chang-Chun, LU Wei-Ping, YAN Yan-Ning. Synthesis of Carbamates by Carbonylation of Floronitrobenzenes over TiO₂ Supported Pd-Fe Catalyst [J]. Chin. J. Org. Chem., 2010, 30(06): 843-848.
[15]	CAO Chen-Zhong, LIU Li-Qiu, CHEN Guan-Fan, ZHOU Zai-Chun, JIANG Rong-Qing, LEI Bing-Chao. Effect of Substituents on the Configuration of Stilbene Derivatives in Wittig Reaction of Substituted Benzaldehyde with Nitro-benzyltriphenylphosphonium Salt [J]. Chin. J. Org. Chem., 2010, 30(03): 395-400.

(CH_3C_5H_4)_3Ln·THF(Ln=Sm,Ho,Tb,Yb)与环戊二烯生成(C_5H_5)_3Ln·THF的新反应

A Novel Reaction of (CH_3C_5H_4)_3Ln·THF (Ln = Sm,Ho,Tb,Yb) with Cyclopentadiene Forming (C_5H_5)_3Ln·THF

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments