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Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (02): 188-192. Previous Articles     Next Articles

Original Articles

具有纳米尺寸的四聚四硫富瓦烯大环冠醚的合成

尹炳柱*,1，温全武1，陈铁1，刘武军1，丛志奇1
金龙一1，和田猛2，西乡和彦2   

  1. (1延边大学理工学院化学系 延吉 133002)
    (2东京大学大学院新领域创成科学研究科 东京 日本 113-8656)
  • 收稿日期:2004-02-23 修回日期:2004-09-08 发布日期:2005-01-15
  • 通讯作者: 尹炳柱

Synthesis of Nanoscale Octathia 36-Crown-12 Annu-latedTetrathiafulvalene Tetramers

YIN Bing-Zhu*,1,WEN Quan-Wu1,CHEN Tie1,LIU Wu-Jun1
CONG Zhi-Qi1,JIN Long-Yi1,WADA Take-shi2,SAIGO Kazuhiko2   

  • Received:2004-02-23 Revised:2004-09-08 Published:2005-01-15
  • Contact: YIN Bing-Zhu

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Cited

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Two nanoscale crown ether annulated tetrathiafulvalene (TTF) tetramers 5a～5b were synthesized via several steps using bis(2-iodoethyl)ether and 2,3-biscyanoethyl TTF derivatives as starting materials by cyanoethyl protection/deprotection method. The electrochemical properties and charge-transfer (CT) interaction with [60]fullerene of open chain TTF tetramer 4b and the above mentioned macrocyclic compound 5b were studied by means of cyclic voltammetry (CV) and 1H NMR spectroscopy, and 5b showed macrocyclic effect and the considerable charge-transfer interaction with [60]fullerene.

Key words: charge-transfer interaction, 36-crown-12 anuulated TTF tetramer, macrocyclic ef-fect