Chin. J. Org. Chem. ›› 2005, Vol. 25 ›› Issue (02): 188-192.
YIN Bing-Zhu*,1,WEN Quan-Wu1,CHEN Tie1,LIU Wu-Jun1CONG Zhi-Qi1,JIN Long-Yi1,WADA Take-shi2,SAIGO Kazuhiko2
Two nanoscale crown ether annulated tetrathiafulvalene (TTF) tetramers 5a～5b were synthesized via several steps using bis(2-iodoethyl)ether and 2,3-biscyanoethyl TTF derivatives as starting materials by cyanoethyl protection/deprotection method. The electrochemical properties and charge-transfer (CT) interaction with fullerene of open chain TTF tetramer 4b and the above mentioned macrocyclic compound 5b were studied by means of cyclic voltammetry (CV) and 1H NMR spectroscopy, and 5b showed macrocyclic effect and the considerable charge-transfer interaction with fullerene.
36-crown-12 anuulated TTF tetramer,
YIN Bing-Zhu*,1,WEN Quan-Wu,CHEN Tie,LIU Wu-JunCONG Zhi-Qi,JIN Long-Yi,WADA Take-shi2,SAIGO Kazuhiko2. Synthesis of Nanoscale Octathia 36-Crown-12 Annu-latedTetrathiafulvalene Tetramers[J]. Chin. J. Org. Chem., 2005, 25(02): 188-192.
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