Study on the temperature effect on the biocatalytic property of a schiff base complex

Chin. J. Org. Chem. ›› 2002, Vol. 22 ›› Issue (2): 145-148. Previous Articles Next Articles

Schiff碱配合物模拟酶催化性能的温度效应研究

陈新斌

湖南大学化学化工学院,长沙(410082)

发布日期:2002-02-25

Study on the temperature effect on the biocatalytic property of a schiff base complex

Chen Xinbin

College of Chemistry & Chemical Engineering, Hunan University, Changsha(410082)

Published:2002-02-25

Abstract

The temperature effects on the catalytic property and the stability of a Schiff base dimanganese complex for the monooxygenation of cyclohexane with PhIO were studied. The results showed that the reaction rate of the catalytic monooxygenation of cyclohexane and the reaction rate of the oxidative destruction of the catalyst by PhIO both regularly increase with the increase of the reaction temperature, and the latter increases more with the increase of the reaction temperature than the former. The best temperature for the catalytic monooxygenation of cyclohexane was found at 25 ℃.

Key words: SCHIFF BASE;DINUCLEAR COMPLEX;SIMULATION;ENZYME;CATALYSIS, AUTO-OXIDATION;REACTION;TEMPERATURE EFFECT

CLC Number:

O643

Cite this article

Chen Xinbin. Study on the temperature effect on the biocatalytic property of a schiff base complex[J]. Chin. J. Org. Chem., 2002, 22(2): 145-148.

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Schiff碱配合物模拟酶催化性能的温度效应研究

Study on the temperature effect on the biocatalytic property of a schiff base complex

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