Transition Metal-Catalyzed Transformations of P(O)—H Bonds

doi:10.6023/cjoc201207024

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (10): 1761-1775.DOI: 10.6023/cjoc201207024 Previous Articles Next Articles

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过渡金属催化磷—氢键的转化反应

徐清^a, 赵长秋^c, 周永波^b, 尹双凤^b, 韩立彪^b,d

a 温州大学化学与材料工程学院温州 325035;
b 湖南大学化学化工学院长沙 410082;
c 聊城大学化学化工学院聊城 252059;
d National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan

收稿日期:2012-07-18 修回日期:2012-08-10 发布日期:2012-08-13
通讯作者: 韩立彪 E-mail:qing-xu@wzu.edu.cn, libiaohan@yahoo.com

Transition Metal-Catalyzed Transformations of P(O)—H Bonds

Xu Qing^a, Zhao Changqiu^c, Zhou Yongbo^b, Yin Shuangfeng^b, Han Libiao^b,d

a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035;
b College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;
c College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059;
d National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan

Received:2012-07-18 Revised:2012-08-10 Published:2012-08-13

Organophosphorus compounds are of high importance in organic synthesis, catalysis, biochemistry, pharmaceuticals, and material science. In this account, we summarize our recent studies on transition metal-catalyzed transformations of P(O)—H compounds, mainly the regio- and stereo-selective additions of P(O)—H bonds to carbon—carbon unsaturated compounds, asymmetric hydrophosphorylation reactions, and oxidative/dehydrogenative cross-couplings of P(O)—H bonds with C—H and heteroatom—H bonds. These new reactions provided a series of efficient and atom economic, general and green ways for the preparation of a variety of versatile organophosphorus compounds. Mechanistic aspects related to the catalytic processes are also discussed.

Key words: transition metal catalysts, P(O)-H compounds, regio- and stereo-selective addition, carbon-carbon unsaturated compounds, oxidative/dehydrogenative cross-coupling, carbon-H and heteroatom-H compounds, fine organophosphorus compounds

Cite this article

Xu Qing, Zhao Changqiu, Zhou Yongbo, Yin Shuangfeng, Han Libiao. Transition Metal-Catalyzed Transformations of P(O)—H Bonds[J]. Chin. J. Org. Chem., 2012, 32(10): 1761-1775.

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过渡金属催化磷—氢键的转化反应

Transition Metal-Catalyzed Transformations of P(O)—H Bonds

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