Self-assembly and Rheological Properties of C12EO4 and Aminosilane Mixtures

doi:10.6023/A13030253

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (08): 1129-1135.DOI: 10.6023/A13030253 Previous Articles Next Articles

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C₁₂EO₄与氨丙基三乙氧基硅烷水溶液自组装和流变性研究

郭红, 王栋, 董姝丽, 窦盈莹, 宋爱新, 郝京诚

山东大学胶体与界面化学教育部重点实验室济南 250100

投稿日期:2013-03-07 发布日期:2013-05-16
通讯作者: 郝京诚, E-mail: jhao@sdu.edu.cn; Tel.: 0531-88366074; Fax: 0531-88564750 E-mail:jhao@sdu.edu.cn
基金资助:
项目受国家自然科学基金(Nos. 21033005, 21273136)和国家重大研究计划(973计划, No. 2009CB930103)资助.

Self-assembly and Rheological Properties of C₁₂EO₄ and Aminosilane Mixtures

Guo Hong, Wang Dong, Dong Shuli, Dou Yingying, Song Aixin, Hao Jingcheng

Key Laboratory for Colloid and Interface Chemistry (Shandong University), Ministry of Education, Jinan 250100

Received:2013-03-07 Published:2013-05-16
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21033005, 21273136) and the National Basic Research Program of China (973 Program, No. 2009CB930103).

Phase behavior, self-assembly, and rheological properties of 3-aminopropyltriethoxysilane (APTES) and nonionic surfactant, CH₃(CH₂)₁₁(OCH₂CH₂)₄OH (C₁₂EO₄), in water were studied. The self-assembled structures were determined by means of small angle X-ray scattering (SAXS), cryo-transmission electron microscopy (cryo-TEM), freeze-fracture TEM (FF-TEM), and ²H nuclear magnetic resonance (²H NMR) measurements and the properties of self-assembled mixtures were obtained by rheological measurements. With a variation of the composition, different self-assembled structures were obtained. In the L_α phase region, a phase structural transition from an aggregate with high curvatures to the lamellar structures with low curvatures is observed with an increase of APTES concentration at a constant concentration of C₁₂EO₄. At constant APTES concentration, with an increase of C₁₂EO₄ concentration, densely packed vesicles and planarly lamellar structures which behave the properties as gel-like solutions having the rather high viscosity coexist. The phase structural transition was considered to be induced by the insertion of the hydrolytic products of APTES into the palisade of the micelles of C₁₂EO₄. These new observations on phase structural transition and self-assembly of nonionic surfactant and aminosilane mixtures could be very important for the full understanding for their applications, especially as templates in the synthesis of silica materials, etc.

Key words: phase behavior, nonionic surfactant, aminosilane, rheological property, cryo-TEM

Cite this article

Guo Hong, Wang Dong, Dong Shuli, Dou Yingying, Song Aixin, Hao Jingcheng. Self-assembly and Rheological Properties of C₁₂EO₄ and Aminosilane Mixtures[J]. Acta Chimica Sinica, 2013, 71(08): 1129-1135.

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C₁₂EO₄与氨丙基三乙氧基硅烷水溶液自组装和流变性研究

Self-assembly and Rheological Properties of C₁₂EO₄ and Aminosilane Mixtures

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C12EO4与氨丙基三乙氧基硅烷水溶液自组装和流变性研究