Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (3): 575-584.DOI: 10.6023/cjoc201709006 Previous Articles     Next Articles

Special Issue: 有机光催化合辑

Reviews

基于光驱动水氧化的有机底物氧化

苗思文, 那永   

  1. 哈尔滨工业大学化工与化学学院 应用化学系 哈尔滨 150001
  • 收稿日期:2017-09-05 修回日期:2017-10-12 发布日期:2017-11-03
  • 通讯作者: 那永,E-mail:yongna@hit.edu.cn E-mail:yongna@hit.edu.cn
  • 基金资助:

    国家自然科学基金(No.21603046)资助项目.

Oxygenation of Organic Substrates Based on Light-Driven Water Oxidation

Miao Siwen, Na Yong   

  1. Department of Applied Chemistry, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001
  • Received:2017-09-05 Revised:2017-10-12 Published:2017-11-03
  • Contact: 10.6023/cjoc201709006 E-mail:yongna@hit.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21603046).

Hydrogen production by artificial photosynthetic water splitting is an efficient approach to convert solar ennergy into chemical bonds. Oxygenation of an organic substrate based on light-driven water oxidation is innovative way to mimic the oxygen evolving center (OEC) in Photosystem Ⅱ. The metal catalyst will accomplish H2O activation to generate high valent metal-oxo intermediate, which can transfer the oxygen atom to an organic substrate, during which the H atoms in H2O molecule could be released. This review is a perspective of the recent advances in oxygenation of organic substrates with water as oxygen source. In the meanwhile, research prospect on photocatalytic hydrogen production coupled with the photocatalytic oxygenation of an organic substrate for a new water splitting system has been proposed.

Key words: artificial photosynthesis, water molecule activation, metal-oxo intermediate, oxygenation of organic substrates