Preparation and Water Tolerance Study of SiO2-supported Perfluorobutylsulfonylimide

doi:10.6023/A1104286

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (03): 311-317.DOI: 10.6023/A1104286 Previous Articles Next Articles

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二氧化硅负载全氟丁基磺酰亚胺的制备与耐水性研究

马忠华^a,b, 杨秋红^a, 马敬中^a

a 华中农业大学理学院化学系武汉 430070;
b 华中科技大学化学与化工学院武汉 430074

投稿日期:2011-04-28 修回日期:2011-08-24 发布日期:2011-11-02
通讯作者: 马忠华 E-mail:mazonghua@mail.hzau.edu.cn
基金资助:
国家自然科学基金(No. 21172083)、中央高校基本科研业务费专项资金(Nos. 2010BQ023, 2011JC004, 2009JC007)资助项目.

Preparation and Water Tolerance Study of SiO₂-supported Perfluorobutylsulfonylimide

Ma Zhonghua^a,b, Yang Qiuhong^a, Ma Jingzhong^a

a Department of Chemistry, College of Basic Sciences, Huazhong Agricultural University, Wuhan 430070;
b School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074

Received:2011-04-28 Revised:2011-08-24 Published:2011-11-02
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21172083) and the Fundamental Research Funds for the Central Universities (Nos. 2010BQ023, 2011JC004, 2009JC007).

A new style of acidic perfluorobutylsulfonylimide-functionalized organosilica (PSFSI-MSMA₁₅/ SiO₂) was synthesized by incorporating a sulfonimide prepolymer (2) into the SiO₂ network. The prepolymer was synthesized by free-radical copolymerization of sodium 4-styrenesulfonyl(perfluorobutylsulfonyl)imide (1) with 3-(trimethoxysilyl)propyl methacrylate (MSMA), and then hydrolyzed and co-condensed with tetraethyl orthosilicate by two-step sol-gel method to afford the acidic hybrid material having acid contents of 0.62 mmol/g. The chemical composition were analyzed by FT-IR, XPS and TG/DTG, and hydrothermal stability was investigated. The results indicated that PSFSI-MSMA₁₅/SiO₂ was high-temperature (210 ℃) and water tolerant. The study of catalytic property and recoverability are in progress.

Key words: perfluorobutylsulfonylimide, hybrid Br?nsted acid, water tolerance, sol-gel method

Cite this article

Ma Zhonghua, Yang Qiuhong, Ma Jingzhong. Preparation and Water Tolerance Study of SiO₂-supported Perfluorobutylsulfonylimide[J]. Acta Chimica Sinica, 2012, 70(03): 311-317.

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二氧化硅负载全氟丁基磺酰亚胺的制备与耐水性研究

Preparation and Water Tolerance Study of SiO₂-supported Perfluorobutylsulfonylimide

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