Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (24): 3013-3018.DOI: 10.6023/A1106071 Previous Articles     Next Articles

Full Papers

氨水/离子液体微乳液(DAIME)的制备及其对木质纤维的物理化学作用

汪滨1, 杨仁党*,1,2, 施伟健1, 刘德桃1, 祝磊1   

  1. (1华南理工大学制浆造纸工程国家重点实验室 广州 510640)
    (2华南理工大学亚热带建筑科学国家重点实验室 广州 510640)
  • 投稿日期:2011-07-07 修回日期:2011-07-15 发布日期:2011-08-17
  • 通讯作者: 杨仁党 E-mail:rdyang@scut.edu.cn
  • 基金资助:

    国家重点基础研究发展规划“973”计划;教育部高校博士点基金;国家自然科学基金;华南理工大学中央高校基本科研业务费项目;制浆造纸工程国家重点实验室开放基金项目

Preparation of Doping Ammonia-Ionic Liquid Microemulsion (DAIME) and Its Physical-Chemistry Effect for lignocellulose

Wang Bin1; Yang Rendang*,1,2; Shi Weijian1; Liu Detao1; Zhu Lei1   

  1. (1 State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640)
    (2 State Key Laboratory of Subtropical Building Science, South China University of Technology, Guangzhou 510640)
  • Received:2011-07-07 Revised:2011-07-15 Published:2011-08-17

The effect of ammonia amounts and doping condition on the stability of 1-butyl-3-methylimidazolium chlorine ([Bmim]Cl)/cyclohexane/n-butanol/cetyl trimethyl ammonium bromide (CTAB) microemulsion were studied. The permeability of DAIME for biomass bamboo and the regularity for pretreatment were investigated further, and characterized by FT-IR and SEM. The DAIME system showed excellent stability after doping ammonia and changing temperature. The effect of ammonia and [Bmim]Cl endowed the DAIME system great permeability which could achieve more than 90%. DAIME pretreatment for biomass material showed perfect selectivity, and the cellulose was well protected, while the lignin had been degraded and removed partially. The lignin removal rate could achieve 33.7% after treating 16 h in 70 ℃. The FT-IR results indicated that the hemicellulose had been acetylated and the chemical bonds between lignin and carbohydrate (LCC) were broken during pretreatment process. The SEM demonstrated that the surface of biomass material significantly showed fault, fracture, and tremendous amount of holes after DAIME pretreatment.

Key words: ionic liquid microemulsion, doping ammonia, permeability, pretreatment