Fluorescence-enhancement Sensor for I- Based on Coumarin in Aqueous Solution

doi:10.6023/A1110104

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (07): 917-920 .DOI: 10.6023/A1110104 Previous Articles Next Articles

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含水溶液中香豆素类探针对碘离子的荧光增强识别

马文辉^a,b, 夏威^b, 徐群^b, 韩宏彦^b, 宋波^b, 孙丽微^b, 梁春花^b

a 齐齐哈尔大学材料科学与工程学院齐齐哈尔 161006;
b 齐齐哈尔大学精细化工黑龙江省普通高校重点实验室齐齐哈尔 161006

投稿日期:2011-10-10 修回日期:2011-12-31 发布日期:2012-02-21
通讯作者: 马文辉
基金资助:
黑龙江省普通高等学校青年学术骨干支持计划(No. 1152G054)和齐齐哈尔市科学技术计划(No. GYGG2010-05-1)资助项目.

Fluorescence-enhancement Sensor for I^- Based on Coumarin in Aqueous Solution

Ma Wenhui^a,b, Xia Wei^b, Xu Qun^b, Han Hongyan^b, Song Bo^b, Sun Liwei^b, Liang Chunhua^b

a School of Materials Science and Engineering, Qiqihar University, Qiqihar 161006;
b Key Laboratory of Fine Chemicals Qiqihar University, College of Heilongjiang Province, Qiqihar 161006

Received:2011-10-10 Revised:2011-12-31 Published:2012-02-21
Supported by:
Project supported by the Young Academic Backbone Project of Heilongjiang Province College (No. 1152G054) and the Science and Technology Plan Project of Qiqihar City (No. GYGG2010-05-1).

A novel fluorescent molecular sensor CI based on coumarin thiosemicarbazide for I^- was designed and synthesized. The structure of CI was identified by 1H NMR, 13C NMR, GC/MS and elemental analysis, and the spectral properties of CI was investigated. In neutral buffer solution, CI exhibited specific recognition for I^- among anions (F^-, Cl^-, Br^-, I^-, AcO^-, HSO₄^-, H₂PO4^- ). The addition of I^- led to 80 nm blue-shift in absorbance maximum, a 6 nm blue-shift in fluorescence maximum, a 5.9-fold fluorescence enhancement and an obvious fluorescence change from yellowish green to brilliant blue. Other anions had no interference for CI to detect I^-.

Key words: fluorescent molecular sensor, I^-, coumarin, thiosemicarbazide, fluorescence enhancement

Cite this article

Ma Wenhui, Xia Wei, Xu Qun, Han Hongyan, Song Bo, Sun Liwei, Liang Chunhua. Fluorescence-enhancement Sensor for I^- Based on Coumarin in Aqueous Solution[J]. Acta Chimica Sinica, 2012, 70(07): 917-920 .

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含水溶液中香豆素类探针对碘离子的荧光增强识别

Fluorescence-enhancement Sensor for I^- Based on Coumarin in Aqueous Solution

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