Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation

doi:10.6023/A1110173

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (08): 1021-1027.DOI: 10.6023/A1110173 Previous Articles Next Articles

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不同取代度纤维素苯甲酸酯负载钌纳米簇催化苯加氢反应

王丽娟^a, 张爱清^a, 李琳^a, 刘汉范^a,b, 刘书正^a

a 中南民族大学催化材料科学湖北省暨国家民委-教育部共建重点实验室武汉 430074;
b 中国科学院化学研究所高分子物理与化学国家重点实验室北京 100080

投稿日期:2011-10-17 修回日期:2012-01-20 发布日期:2012-01-20
通讯作者: 张爱清 E-mail:aiqingzhang_2000@sina.com
基金资助:
国家自然科学基金(No. 20774108)资助项目.

Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation

Wang Lijuan^a, Zhang Aiqing^a, Li Lin^a, Liu Hanfan^a,b, Liu Shuzheng^a

a Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission and Ministry of Education, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, China;
b State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Received:2011-10-17 Revised:2012-01-20 Published:2012-01-20
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20774108).

Cellulose benzoyl ester (CB) was synthesized from cellulose and benzoyl chloride. Different substitution degree CBs were obtained by controlling the amount of benzoyl chloride, and the resulting CBs have different swelling degree in benzene, cyclohexene and cyclohexane. Hybrid membrane, which was used for the selective hydrogenation, was prepared by supporting Ru nano-clusters (obtained by refluxing reduction of RuCl3 with n-butyl alcohol) into CB. CBs and the hybrid membranes were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and transmission electron microscope (TEM), etc. Research results demonstrated that swelling behavior acts as a crucial factor to the selectivity of cyclohexene. Active evaluation results indicated that the conversion of benzene (highest, 2.8%) increased while the selectivity of cyclohexene (highest, 53.4%) decreased with the increasing of CBs substitution degree.

Key words: Ru nano-cluster, cellulose benzoyl ester, benzene, cyclohexene, swelling

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Wang Lijuan, Zhang Aiqing, Li Lin, Liu Hanfan, Liu Shuzheng. Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation[J]. Acta Chimica Sinica, 2012, 70(08): 1021-1027.

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不同取代度纤维素苯甲酸酯负载钌纳米簇催化苯加氢反应

Cellulose Benzoyl Ester with Different Substitution Degree Supported Ru Nano-clusters Catalyst for Benzene Hydrogenation

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