Application of Fourier Transform Infrared Spectroscopy Combined with Pattern Recognition Method for Rapid Authentication of Edible Oil

doi:10.6023/A1110193

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (08): 995-1000.DOI: 10.6023/A1110193 Previous Articles Next Articles

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傅里叶变换红外光谱结合模式识别法快速鉴别食用油的真伪

刘玲玲^a,b, 武彦文^b, 张旭^b, 欧阳杰^a, 李冰宁^b, 侯敏^b, 陈舜琮^b

a 北京林业大学生物科学与技术学院食品科学与工程系北京 100083;
b 北京市理化分析测试中心北京市食品安全分析测试工程技术研究中心北京 100089

投稿日期:2011-10-19 修回日期:2012-01-18 发布日期:2012-02-06
通讯作者: 欧阳杰 E-mail:chemist003@sohu.com
基金资助:
北京市自然科学基金(No. 7102021)资助项目.

Application of Fourier Transform Infrared Spectroscopy Combined with Pattern Recognition Method for Rapid Authentication of Edible Oil

Liu Lingling^a,b, Wu Yanwen^b, Zhang Xu^b, Ouyang Jie^a, Li Bingning^b, Hou Min^b, Chen Shuncong^b

a Department of Food Science and Engineering, College of Biological Sciences and Technology, Beijing Forestry University, Beijing 100083;
b Beijing Engineering Research Center of Food Safety Analysis, Beijing Center for Physical and Chemical Analysis, Beijing 100089

Received:2011-10-19 Revised:2012-01-18 Published:2012-02-06
Supported by:
Project supported by the Natural Science Foundation of Beijing (No. 7102021).

The rapidly analytical method for authenticity of edible oil was established by Fourier transform infrared spectroscopy (FTIR) combined with soft independent modeling of class analogy (SIMCA). Based on fingerprint characteristics of FTIR, the spectra of 53 qualified edible oils and 13 false edible oils were analyzed. After preprocessing these spectra data with second derivative and normalization, principal component analysis (PCA) was used to extract the characteristic variables in pattern recognition. Then, 43 qualified oils and 9 false oils were selected as training set to establish SIMCA classification model. And the model was validated by other 10 qualified oils and 4 false oils as validation set with the correct recognition rate of 100%. The results demonstrated that FTIR combined with chemometrics could be alternatively used to rapidly and simply determine the authenticity of edible oil.

Key words: edible oils, authentication, FTIR, SIMCA

Cite this article

Liu Lingling, Wu Yanwen, Zhang Xu, Ouyang Jie, Li Bingning, Hou Min, Chen Shuncong. Application of Fourier Transform Infrared Spectroscopy Combined with Pattern Recognition Method for Rapid Authentication of Edible Oil[J]. Acta Chimica Sinica, 2012, 70(08): 995-1000.

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References

1 Jiao, Y. P. Modern Food Sci. Tech. 2008, 24, 378 (in Chinese). (焦云鹏, 现代食品科技, 2008, 24, 378.)

2 Wang, L.; Liu, Y. G.; Chen, F. F.; Hu, J. H. J. Wuhan Polytech. Univ. 2007, 26, 2 (in Chinese). (王乐, 刘尧刚, 陈凤飞, 胡健华, 武汉工业学院学报,2007, 26, 2.)

3 Pan, J. Y.; Yin, P. H.; Yu, H. H.; Shan, X. Z.; Deng, C. H.; Zhao, L. Food Sci. 2003, 24, 27 (in Chinese). (潘剑宇, 尹平河, 余汉豪, 单习章, 邓彩虹, 赵玲, 食品科学, 2003, 24, 27.)

4 Zhu, R.; Wang, D.; Yang, X. J.; He, D. P. Cereals and Oils,2008, 11, 42 (in Chinese). (朱锐, 王督, 杨小京, 何东平, 粮食与油脂, 2008, 11,42.)

5 Wang, L.; Li, Y.; Hu, J. H. China Oils and Fats 2008, 33,75 (in Chinese). (王乐, 黎勇, 胡健华, 中国油脂, 2008, 33, 75.)

6 Yin, P. H.; Pan, J. Y.; Zhao, L.; Zhang X.; Wang, G. C.; Yu, H. H.; Shan, X. Z. China Oils and Fats 2004, 29, 47 (in Chinese). (尹平河, 潘剑宇, 赵玲, 张璇, 王国翠, 余汉豪, 单习章, 中国油脂, 2004, 29, 47.)

7 Wu, Y. W.; Sun, S. Q.; Zhou, Q.; Tao, J. X.; Noda, I. J. Mol. Struct. 2008, 882, 107.

8 Wu, Y. W.; Sun, S. Q.; Zhou, Q.; Leung, H. W. J. Pharm. Biomed. Anal. 2008, 46, 498.

9 Chu, X. L. Molecular Spectroscopy Analytical Technology Combined with Chemometrics and Its Application, Chemical Industry Press, Beijing, 2011, p. 95 (in Chinese). (禇小立, 化学计量学方法与分子光谱分析技术, 北京, 化学工业出版社, 2011, p. 95.)

10 Yang, Z.; Jiang, Z. H.; Fei, B. H.; Qin, D. C. Spectrosc. Sepctr. Anal. 2007, 27, 686 (in Chinese). (杨忠, 江泽慧, 费本华, 覃道春, 光谱学与光谱分析,2007, 27, 686.)

11 Yu, C. X.; Ma, X.; Zhang, Y. H.; Li, J. H.; Zhao, L. L.; Xu, L.; Wen, Y. D.; Wang, Y.; Zhang, L. D. Spectrosc. Sepctr. Anal. 2011, 31, 924 (in Chinese). (于春霞, 马翔, 张晔晖, 李军会, 赵龙莲, 许莉, 温亚东, 王毅, 张录达, 光谱学与光谱分析, 2011, 31, 924.)

12 Li, J.; Fan, L.; Bi, Y. L.; Qu, L. B.; Zhou, Z. M.; Wu, C. R. Chinese J. Anal. Chem. 2010, 38, 475 (in Chinese). (李娟, 范璐, 毕艳兰, 屈凌波, 周展明, 吴存荣, 分析化学, 2010, 38, 475.)

13 Van de Voort, F. R.; Ghetler, A.; Garcia-Gonzalez, D. L.; Li, Y. D. Food Anal. Method 2008, 1, 153.

14 Climaco Pinto, R.; Locquet, N.; Eveleigh, L.; Rutledge, D. N. Food Chem. 2010, 120, 1170.

15 Xu, R.; Sun, S. Q.; Liu, Y. G.; Yu, J.; Zhou, F.; Liu, T. N.; Chen, J.; Chen, S. L. Spectrosc. Sepctr. Anal. 2009, 29,

1860 (in Chinese). (徐荣, 孙素琴, 刘友刚, 于晶, 周峰, 刘同宁, 陈君, 陈士林, 光谱学与光谱分析, 2009, 29, 1860.)

16 Sun, S. Q.; Tang, J. M.; Yuan, Z. M.; Bai, Y. Spectrosc. Sepctr. Anal. 2003, 23, 258 (in Chinese). (孙素琴, 汤俊明, 袁子民, 白雁, 光谱学与光谱分析,2003, 23, 258.)

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傅里叶变换红外光谱结合模式识别法快速鉴别食用油的真伪

Application of Fourier Transform Infrared Spectroscopy Combined with Pattern Recognition Method for Rapid Authentication of Edible Oil

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