Studies on Preparation of Cd2+ Ion Surface-Imprinted Material with High Ion Recognition Ability and Its Ion Recognition Mechanism

doi:10.6023/A12121106

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (03): 409-416.DOI: 10.6023/A12121106 Previous Articles Next Articles

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具有高离子识别能力的镉离子表面印迹材料的制备及其离子识别机理的研究

房晓琳^a, 高保娇^a, 黄小卫^b, 张永奇^b, 顾来沅^a

a 中北大学化学工程系太原 030051;
b 北京有色金属研究总院北京 100088

投稿日期:2012-12-27 发布日期:2013-01-04
通讯作者: 高保娇 E-mail:gaobaojiao@126.com
基金资助:
项目受国家青年科学基金(No.51104023)资助.

Studies on Preparation of Cd²⁺ Ion Surface-Imprinted Material with High Ion Recognition Ability and Its Ion Recognition Mechanism

Fang Xiaolin^a, Gao Baojiao^a, Huang Xiaowei^b, Zhang Yongqi^b, Gu Laiyuan^a

a Department of Chemical Engineering, North University of China, Taiyuan 030051;
b General Research Institute for Nonferrous Metals, Beijing 100088

Received:2012-12-27 Published:2013-01-04
Supported by:
Project supported by the National Science Foundation for Young Scientists of China (No. 51104023).

1. Studies on Preparation of Cd²⁺ Ion Surface-Imprinted Material with High Ion Recognition Ability and Its Ion Recognition Mechanism.PDF(98KB)

Abstract

Hydroxyethyl methacrylate (HEMA) was graft-polymerized on micron-sized silica gel particles via surface- initiated graft-polymerization with amino/persulfate redox initiating system, obtaining the grafted particles PHEMA/SiO₂ with a high grafting degree. Subsequently, the nucleophilic substitution reaction between the grafted PHEMA and 5-chloromethyl-8-hydroxyquinoline (CHQ) was carried out, and the 8-hydroxyquinoline-functionalization transformation of the grafted particles PHEMA/SiO₂ was realized, preparing the functional grafted particles HQ-PHEMA/SiO₂. The strong chelating adsorption property of HQ-PHEMA/SiO₂ towards Cd²⁺ ion was deeply investigated. On that basis, the ion imprinting towards the functional grafted macromolecules HQ-PHEMA was conducted with Cd²⁺ ion as the template ion and dichloroether as crosslinker by using the novel surface imprinting technique found by our research group, and Cd²⁺ ion surface-imprinted material IIP-HQP/SiO₂ was prepared. The ion recognition and combination characters of IIP-HQP/SiO₂ were examined in detailed. The experimental results show that this ion imprinted material has excellent recognition selectivity and combination affinity for the template ion, Cd²⁺ ion. Relative to Cu²⁺ and Pb²⁺ ions as two contrast ions, the selectivity coefficients of IIP-HQP/SiO₂ for Cd²⁺ ion reach up to 25.52 and 22.91, respectively, displaying ultrahigh ion recognition ability.

Key words: heavy metal ion, ion surface-imprinting, graft polymerization, 8-hydroxyquinoline, chelation adsorption, ion recognition

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Fang Xiaolin, Gao Baojiao, Huang Xiaowei, Zhang Yongqi, Gu Laiyuan. Studies on Preparation of Cd²⁺ Ion Surface-Imprinted Material with High Ion Recognition Ability and Its Ion Recognition Mechanism[J]. Acta Chimica Sinica, 2013, 71(03): 409-416.

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具有高离子识别能力的镉离子表面印迹材料的制备及其离子识别机理的研究

Studies on Preparation of Cd²⁺ Ion Surface-Imprinted Material with High Ion Recognition Ability and Its Ion Recognition Mechanism

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