A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties

doi:10.6023/A13010121

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (05): 755-760.DOI: 10.6023/A13010121 Previous Articles Next Articles

Special Issue: 纪念南开大学化学学科创建100周年

Article

基于线性叠氮四核单元的系列二维化合物: 合成, 晶体结构及磁性

李佐习, 杨乾, 李立存, 胡同亮, 卜显和

南开大学化学系金属与分子基材料化学天津市重点实验室天津 300071

投稿日期:2013-01-24 发布日期:2013-03-26
通讯作者: 胡同亮,tlhu@nankai.edu.cn E-mail:tlhu@nankai.edu.cn
基金资助:
项目受国家自然科学基金(Nos. 21031002, 51073079)和天津市自然科学基金(No. 11JCYBJC04100)资助.

A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties

Li Zuoxi, Yang Qian, Li Licun, Hu Tongliang, Bu Xianhe

Department of Chemistry, and Tianjin Key Laboratory of Metal & Molecule-based Material Chemistry, Nankai University, Tianjin 300071

Received:2013-01-24 Published:2013-03-26
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21031002, 51073079) and the Natural Science Fund of Tianjin, China (No. 11JCYBJC04100).

1. A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties.PDF(88KB)

Abstract

Sparked by the strategy of molecular magnets, three magnetic coordination polymers, [Co₂(N₃)₄(L)_2.5]_∞ (1), [Ni₂(N₃)₃(NO₃)(L)_2.5]_∞ (2) and [Mn₂(N₃)₄(L)_2.5]_∞ (3) (L=4,4'-bis(imidazol-1-yl)biphenyl), have been synthesized by employing azide as the coupling carrier and a rod-like ligand L as the magnetic insulator. Structural analysis indicates that complexes 1～3 are iso-structural, and illustrate a 2D (4,4) layer based on unprecedented linear tetranuclear units bridged by the EO-azido ions. Their magnetic measurements revealed that complexes 1～3 all present the ferromagnetic (FM) coupling, which was due to the EO-azido linker. The corresponding exchange coupling constants have been estimated by fitting the experimental data, which confirmed the above magneto-structural correlations.

Key words: coordination polymer, rod-like ligand, linear tetranuclear cluster, magnetic property

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Li Zuoxi, Yang Qian, Li Licun, Hu Tongliang, Bu Xianhe. A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties[J]. Acta Chimica Sinica, 2013, 71(05): 755-760.

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基于线性叠氮四核单元的系列二维化合物: 合成, 晶体结构及磁性

A Series of 2D Coordination Polymers Based on Unprecedented Linear Tetranuclear Units Bridged by the Azido Anion: Syntheses, Crystal Structures and Magnetic Properties

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