Polyynes with Aggregation-Induced Emission Characteristics: Synthesis and Their Photonic Properties

doi:10.6023/A16070348

Acta Chim. Sinica ›› 2016, Vol. 74 ›› Issue (11): 877-884.DOI: 10.6023/A16070348 Previous Articles Next Articles

Article

具有聚集诱导发光效应的聚炔材料的合成及光学性能研究

韩婷^a,b, 詹嘉慧^a,b, 林荣业^a,b, 唐本忠^a,b

a 香港科技大学化学系国家人体组织功能重建工程技术研究中心香港分中心香港九龙清水湾;
b 香港科技大学深圳研究院深圳 518057

投稿日期:2016-07-16 发布日期:2016-08-24
通讯作者: 林荣业, 唐本忠 E-mail:chjacky@ust.hk;tangbenz@ust.hk
基金资助:
项目受国家基础研究发展规划项目（973项目；2013CB834701，2013CB834702），香港大学教育资助委员会（AoE/P-03/08），国家自然科学基金（21490570和21490574），香港研究资助局（604913，16305014，16303815）及创新科技署（ITC-CNERC14S01）资助.同时感谢广东省创新科研团队项目（201101C0105067115）资助.

Polyynes with Aggregation-Induced Emission Characteristics: Synthesis and Their Photonic Properties

Han Ting^a,b, Cathy K. W. Jim^a,b, Jacky W. Y. Lam^a,b, Tang Ben Zhong^a,b

a Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute for Advanced Study, Institute of Molecular Functional Materials, Division of Biomedical Engineering, Division of Life Science and State Key Laboratory of Molecular Neuroscience, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China;
b HKUST-Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park, Nanshan, Shenzhen 518057, China

Received:2016-07-16 Published:2016-08-24
Supported by:
Project supported by the National Basic Research Program of China (973 Program; 2013CB834701, 2013CB834702), the University Grants Committee of Hong Kong (AoE/P-03/08), the National Natural Science Foundation of China (21490570, 21490574), the Research Grants Council of Hong Kong (604913, 16305014 and 16303815), and the Innovation and Technology Commission (ITC-CNERC14S01). B.Z.T. thanks the support of the Guangdong Innovative Research Team Program (201101C0105067115).

1. Polyynes with Aggregation-Induced Emission Characteristics: Synthesis and Their Photonic Properties.PDF(681KB)

Abstract

Tetraphenylethene-containing diacetylenes are synthesized and their homopolymerizations are catalyzed by CuCl in o-dichlorobenzene, furnishing linear polyynes in high isolated yields. All polymers possess good solubility in common organic solvents and enjoy high thermal stability. Whereas they are practically non-emissive when molecularly dissolved in good solvents, they become highly emissive when aggregated as nanoparticle suspensions in poor solvents or fabricated into thin films in the solid state, demonstrating a novel phenomenon of aggregation-induced emission. The polymers are highly transparent, allowing almost all light in the entire visible spectral region to transmit through. Thin films of the polymers show high refractive indices (n=1.7787~1.6543) in the wavelength region of 400~1700 nm and very low chromatic aberrations (D'=0.0003). Their n values can be modulated and their thin films can be crosslinked by UV irradiation, generating fluorescent patterns with high resolutions.

Key words: linear polyynes, aggregation-induced emission, tetraphenylethene, refractive index

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Han Ting, Cathy K. W. Jim, Jacky W. Y. Lam, Tang Ben Zhong. Polyynes with Aggregation-Induced Emission Characteristics: Synthesis and Their Photonic Properties[J]. Acta Chim. Sinica, 2016, 74(11): 877-884.

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具有聚集诱导发光效应的聚炔材料的合成及光学性能研究

Polyynes with Aggregation-Induced Emission Characteristics: Synthesis and Their Photonic Properties

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