Heterogeneous Reaction of NH3 and Cl2 on the Surface of γ-Al2O3 Particles

doi:10.6023/A18090401

Acta Chim. Sinica ›› 2019, Vol. 77 ›› Issue (2): 160-165.DOI: 10.6023/A18090401 Previous Articles Next Articles

Article

NH₃与Cl₂在γ-Al₂O₃颗粒物表面的非均相反应

唐思群^a,b, 马玲玲^a, 罗敏^a, 张朝晖^c, 邱烨^c, 冯烁^c, 夏传琴^b, 金永东^b, 徐殿斗^a

a 中国科学院高能物理研究所核技术应用研究中心北京 100049;
b 四川大学化学学院成都 610064;
c 北京出入境检验检疫局检验检疫技术中心北京 100026

投稿日期:2018-09-25 发布日期:2018-12-05
通讯作者: 马玲玲,E-mail:malingling@ihep.ac.cn;徐殿斗,E-mail:xudd@ihep.ac.cn E-mail:malingling@ihep.ac.cn;xudd@ihep.ac.cn
基金资助:
项目受国家自然科学基金（Nos.U1832212，11405184，11575210，91643206）和中科院重点部署项目（No.ZDRW-CN-2018-1）资助.

Heterogeneous Reaction of NH₃ and Cl₂ on the Surface of γ-Al₂O₃ Particles

Tang Siqun^a,b, Ma Lingling^a, Luo Min^a, Zhang Zhaohui^c, Qiu Ye^c, Feng Shuo^c, Xia Chuanqin^b, Jin Yongdong^b, Xu Diandou^a

a Division of Nuclear Technology and Applications, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049;
b College of Chemistry, Sichuan University, Chengdu 610064;
c Beijing Entry-Exit Inspection and Quarantine Bureau Technology Centre, Beijing 100026

Received:2018-09-25 Published:2018-12-05
Contact: 10.6023/A18090401 E-mail:malingling@ihep.ac.cn;xudd@ihep.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. U1832212, 11405184, 11575210, 91643206) and the Key Deployment Projects of Chinese Academy of Sciences (No. ZDRW-CN-2018-1).

The effect of NH₃ concentration, reaction time and other conditions on the heterogeneous reaction of NH₃ and Cl₂ on the surface of γ-Al₂O₃ particles was investigated at the room temperature, pressure and in the presence of oxygen by ion chromatography (IC). The formation of the surface species (Cl^-, NO₃^-, and SO₄^2-) via both individual reaction and co-existing reaction of NH₃, Cl₂, SO₂ and NO₂ on the surface of γ-Al₂O₃ was investigated as well. The results revealed that NH₃ (400 ppm) and Cl₂ (400 ppm) had synergistic effect on the surface γ-Al₂O₃, and the total yield of Cl^- was 589.65 μg after reaction of 2 h. The formation of the surface chlorides increased firstly and then decreased with the increase of ammonia concentration, and the maximum yield of Cl^- was reached at 400 ppm of NH₃. In the presence of active chlorine, NH₃ significantly promoted the generation of the adsorptive species on the surface, such as Cl^-, NO₃^- and SO₄^2-, and the most obvious synergistic effect was induced to form on the conditions of four gases co-existence. The heterogeneous reaction mechanism of NH₃ with Cl₂ and the influence on the atmospheric environment were also discussed as well. Additionally, the mixing ratios used in the study are extremely high compared with ambient levels, which could be as a simulation to explore whether the synergistic effect obtained in this paper are also present in the real ambient conditions. We have studied a relatively low mixing ratios for heterogeneous reaction experiments, but the content of nitrate and chloride on the surface of γ-Al₂O₃ were lower than the limit of detection of ion chromatography. Therefore, other researches such as Knudsen cell and smog chamber study, field monitoring, and mode study are also worth for exploring in future study. The results of this study could provide reference data for the study of the contribution of active chlorine and ammonia to the formation of secondary inorganic particles.

Key words: heterogeneous reaction, secondary inorganic particles, NH₃, Cl₂

Cite this article

Tang Siqun, Ma Lingling, Luo Min, Zhang Zhaohui, Qiu Ye, Feng Shuo, Xia Chuanqin, Jin Yongdong, Xu Diandou. Heterogeneous Reaction of NH₃ and Cl₂ on the Surface of γ-Al₂O₃ Particles[J]. Acta Chim. Sinica, 2019, 77(2): 160-165.

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NH₃与Cl₂在γ-Al₂O₃颗粒物表面的非均相反应

Heterogeneous Reaction of NH₃ and Cl₂ on the Surface of γ-Al₂O₃ Particles

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NH3与Cl2在γ-Al2O3颗粒物表面的非均相反应