Doping of Organic Semiconductors with Lewis Base Anions: Mechanism, Applications and Perspectives

doi:10.6023/A20080342

Acta Chimica Sinica ›› 2020, Vol. 78 ›› Issue (12): 1287-1296.DOI: 10.6023/A20080342 Previous Articles Next Articles

Perspective

路易斯碱负离子掺杂有机半导体:原理、应用和展望

蒋丹妮, 严康荣, 李昌治

浙江大学高分子科学与工程学系杭州 310027

投稿日期:2020-08-02 发布日期:2020-09-04
通讯作者: 李昌治 E-mail:czli@zju.edu.cn
作者简介:蒋丹妮,浙江大学高分子科学与工程学系高分子材料专业2019级硕士生,主要研究方向为有机半导体的可控掺杂和有机太阳电池.
严康荣,浙江大学高分子科学与工程学系高分子材料专业2016级博士生.主要研究方向为富勒烯材料以及有机和钙钛矿太阳电池中界面材料的合成.
李昌治,浙江大学"百人计划"研究员、博士生导师.从事有机半导体材料化学和光电转换清洁能源方面的基础研究和应用开发,从分子的设计、合成和组装研究入手,发展高性能光电材料和能量转换器件.近五年,围绕光电转换过程中一个基础共性问题:"半导体异质界面电荷输运",工作中发展了路易斯碱负离子可控掺杂有机半导体方法和路易斯酸碱作用调谐界面的分子策略与材料,通过创新的方法和自主材料实现了高效界面电荷输运,成功构建了高性能光电器件.至今发表120余篇SCI论文,包括Nature,Nature Comm.,J.Am.Chem.Soc.,Adv.Mater.等期刊,论文篇均影响因子大于10,入选英国皇家化学学会能源和可持续性领域2019年度的Top 1%高被引作者和科睿唯安发布的2019年全球高被引科学家.
基金资助:
项目受国家自然科学基金优秀青年项目（No.21722404），面上项目（No.21674093）和浙江省自然科学基金杰出青年项目（No.LR17E030001）资助.

Doping of Organic Semiconductors with Lewis Base Anions: Mechanism, Applications and Perspectives

Jiang Dan-Ni, Yan Kang-Rong, Li Chang-Zhi

Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Received:2020-08-02 Published:2020-09-04
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21722404, 21674093), and Zhejiang Natural Science Fund for Distinguished Young Scholars (No. LR17E030001).

Doping is an effective method to improve the carrier densities and charge transport capabilities of organic semiconductors. In recent years, n-doping of organic semiconductors via Lewis base anions has attracted much attentions of researchers, which takes place under mild condition and controllable fashion, hence exhibiting broad applications in optoelectronics. This perspective focuses on discussing the mechanism of anion-induced electron transfer to semiconductors, summarizing its recent progresses in interfacial materials and doped active layers for optoelectronic devices, as well as analyzing the future development of this field.

Key words: Lewis base anions, n-doping, anion-π interaction, interfacial materials, dopant

Cite this article

Jiang Dan-Ni, Yan Kang-Rong, Li Chang-Zhi. Doping of Organic Semiconductors with Lewis Base Anions: Mechanism, Applications and Perspectives[J]. Acta Chimica Sinica, 2020, 78(12): 1287-1296.

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路易斯碱负离子掺杂有机半导体:原理、应用和展望

Doping of Organic Semiconductors with Lewis Base Anions: Mechanism, Applications and Perspectives

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