In Situ/Operando Advances of Electrode Processes in Solid-state Lithium Batteries

doi:10.6023/A21060255

Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (10): 1197-1213.DOI: 10.6023/A21060255 Previous Articles Next Articles

Review

固态锂电池电极过程的原位研究进展

田建鑫^a^,^b, 郭慧娟^a^,^b, 万静^a^,^b, 刘桂贤^a^,^b, 严会娟^a^,^b, 文锐^a^,^b^,^*(), 万立骏^a^,^b

a 中国科学院化学研究所中国科学院分子纳米结构与纳米技术重点实验室中国科学院分子科学科教融合卓越中心北京分子科学国家研究中心北京 100190
b 中国科学院大学北京 100049

投稿日期:2021-06-07 发布日期:2021-08-27
通讯作者: 文锐

作者简介:

田建鑫, 中国科学院化学研究所分子纳米结构与纳米技术重点实验室2019级硕士研究生, 主要从事固态锂电池正极过程的原位研究.

郭慧娟, 中国科学院化学研究所分子纳米结构与纳米技术重点实验室2018级博士研究生, 主要从事固态锂电池正极过程的原位研究.

万静, 中国科学院化学研究所分子纳米结构与纳米技术重点实验室2017级博士研究生, 主要从事固态锂电池负极过程的原位研究.

刘桂贤, 中国科学院化学研究所分子纳米结构与纳米技术重点实验室2018级博士研究生, 主要从事固态Li-S电池负极过程的原位研究.

严会娟, 中国科学院化学研究所分子纳米结构与纳米技术重点实验室副研究员, 研究方向为扫描探针显微技术及应用.

文锐, 中国科学院化学研究所分子纳米结构与纳米技术重点实验室研究员、博士生导师, 国家自然科学基金优秀青年科学基金获得者, 主要研究领域是界面电化学.

万立骏, 中国科学院院士, 发展中国家科学院院士, 中国科学院化学研究所研究员、博士生导师, 国家杰出青年科学基金获得者, 主要从事扫描探针显微学、电化学和纳米材料科学的研究.

基金资助:
国家重点研发计划(2016YFA0202500); 国家自然科学基金优秀青年科学基金(21722508)

In Situ/Operando Advances of Electrode Processes in Solid-state Lithium Batteries

Jianxin Tian^a^,^b, Huijuan Guo^a^,^b, Jing Wan^a^,^b, Guixian Liu^a^,^b, Huijuan Yan^a^,^b, Rui Wen^a^,^b(), Lijun Wan^a^,^b

a Institute of Chemistry Chinese Academy of Sciences, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Beijing National Laboratory for Molecular Sciences, Beijing 100190, China
b University of Chinese Academy of Sciences, Beijing 100049, China

Received:2021-06-07 Published:2021-08-27
Contact: Rui Wen
Supported by:
National Key R&D Program of China(2016YFA0202500); National Natural Science Fund for Excellent Young Scholars(21722508)

Solid-state lithium batteries (SSLBs) are considered to be an important development direction for the next generation of power batteries due to their safety and potentially high energy density. However, there are several challenges including low ionic conductivity, poor stability/incompatibility between electrodes and electrolytes at present. To improve the performance of SSLBs, it is very important to clarify the dynamic evolution of electrodes, solid electrolytes, and their interfaces in the cycle process. In the past few decades, the emergence of various advanced in-situ characterization technologies has improved the understanding of the working mechanism of high-performance lithium batteries and promoted further development. Herein, we present a comprehensive overview of the in situ research progress of atomic force microscope, electron microscope, X-ray microscope and other imaging characterization techniques, and component analysis techniques such as Raman spectroscopy, X-ray technology, and neutron depth analysis in recent years. The focus is on the application research of various characterization techniques in morphology and composition evolution processes of the SSLBs, including the phase transformation and deformation of the cathode materials, the deposition/dissolution of lithium metal, the growth of lithium dendrites, the structure evolution of solid electrolytes, and the formation of the solid electrolyte interphase, which strengths the understanding of solid-state lithium batteries.

Key words: solid-state lithium battery, electrode process, solid electrolyte interphase, in situ technology

Cite this article

Jianxin Tian, Huijuan Guo, Jing Wan, Guixian Liu, Huijuan Yan, Rui Wen, Lijun Wan. In Situ/Operando Advances of Electrode Processes in Solid-state Lithium Batteries[J]. Acta Chimica Sinica, 2021, 79(10): 1197-1213.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 14

Figure 1. Schematic illustration of in situ characterization techniques of electrode processes in solid-state lithium batteries

	光学显微镜(OM)	扫描电子显微镜(SEM)	透射电子显微镜(TEM)	原子力显微镜(AFM)	X-ray computed tomo- graphy microscopy
探测源	可见光、激光等	电子束	电子束	探针	X-ray
样品操作环境	大气、真空及液相	真空	真空	大气、真空及液相	大气或真空
空间分辨率	200 nm	2 nm	0.1 nm	0.1 nm (Z)	50 nm
优势	时间分辨率高、对样品要求低	2~20万的放大倍数连续可调、景深大	同时获得样品形貌、晶体学和微观结构信息	对样品侵扰性小、 3D表面成像	无损3D成像
劣势	空间分辨率低	2D成像、不利于测量对电子束敏感的样品	制样复杂、不利于测量对电子束敏感的样品	受限于表面粗糙度、成像范围小	轻元素对比度较弱

Table 1. Comparison of imaging techniques

Figure 2. In situ TEM studies for cathode, anode and solid eletrolyte interphase. (a) In situ TEM set-up. Reproduced with permission[37]. Copyright 2016, American Chemical Society. (b) Cathode materials of LiCoO2: the monocrystal-polycrystal transition, formation of antiphase domain boundaries and coherent twin boundaries. Reproduced with permission[48]. Copyright 2017, American Chemical Society. (c) The reaction between Li tip and LCO/SRO (SrRuO3)/STO(SrTiO3)(001). Reproduced with permission[22]. Copyright 2018, Wiley. (d) The Li plating/stripping cycle on a N-HPCS. Reproduced with permission[52]. Copyright 2020, Wiley. (e) In situ charge-density-distribution characterization of the LCO/LPSCl interface with bias voltages of 1.0 V, 1.2 V, 1.4 V, 1.6 V, 2.0 V and 2.2 V. Reproduced with permission[55]. Copyright 2020, Nature

Figure 3. (a) Schematic of the basic principle of AFM. (b) In situ AFM electrochemical cell

	成像模式	探测的物理量
基本模式	轻敲模式AFM	悬臂振幅A
	接触模式AFM	悬臂弯曲度D
	扭转共振模式AFM	悬臂扭转量t
	峰值力AFM	探针-样品间的相互作用F
功能化模式	相位成像(Phase imaging)	悬臂振动相位φ
	横向力显微镜LFM	针尖-样品横向力L
	磁力显微镜MFM	悬臂振动相位φ或频率ω
	开尔文探针显微镜KPFM	样品表面电势V
	导电原子力显微镜C-AFM	针尖-样品间的电流
	扫描电化学显微镜SECM	样品电容随交变电压的变化率dC/dV

Table 2. Common imaging modes of AFM

Figure 4. In situ AFM images: (a) Topography images of SCEs: a-e) discharging and f-h) charging during the first cycle. Reproduced with permission[68]. Copyright 2020, Wiley. (b) Morphological evolution of the SEI shell on the In electrode upon lithiation/delithiation. a) Cyclic voltammogram curve. b-g, i-n, p) AFM images and corresponding DMT modulus mappings on the In electrode at different potentials. h, m) Height section profiles of the electrode surfaces. o) 3D AFM images of the wrinkle structures. Reproduced with permission[69]. Copyright 2021, American Chemical Society. (c) Evolution of CEI film on NCM523 electrode. a-g) Morphology and a′-g′) mapping of the DMT modulus. h) The gauss statistic distribution histograms of the film thickness. i) Average DMT modulus of the electrode surface. Reproduced with permission[70]. Copyright 2020, American Chemical Society

Figure 5. In situ SEM topography images. (a) SEM experimental setup. Reproduced with permission[72]. Copyright 2018, American Chemical Society. (b) Cross-sectional morphology evolution of the lithium dendrite penetrates the LLZTO: topography images and schematic illustration. Reproduced with per- mission[27]. Copyright 2019, Elsevier. (c) Evolution of solid sulfur species in Li-S cell. Reproduced with permission[74]. Copyright 2016, Elsevier

Figure 6. In situ OM studies. (a) Li plating/stripping processes at different potentials. Reproduced with permission[59]. Copyright 2020, Wiley. (b) Evolution of the cathode electrolyte interphase. Reproduced with permission[78]. Copyright 2019, The Royal Society of Chemistry. (c) Mechanical stress of Ga-doped LLZO ceramic pellet contacting with Li foil. Reproduced with permission[79]. Copyright 2019, Elsevier

Figure 7. In situ X-ray images. (a) Mechanical degradation of LAGP within a Li/LAGP/Li cell: A) 2D slices from the center of the LAGP pellet extracted from the 3D tomogram. B) 3D crack networks shown throughout the entire LAGP pellet. Reproduced with permission[82]. Cop- yright 2019, American Chemical Society. (b) Operando X-ray spectro- scopic nanotomography: phase distribution, cut-view of FeS2 at lithiated state, the XANES spectra of standard FeS2 and Fe and phase volume fraction obtained from 3D quantitative analysis. Reproduced with permis- sion[83]. Copyright 2019, Wiley

Figure 8. In situ Raman spectra. (a) Li-S batteries: changes of sulfur species. Reproduced with permission[68]. Copyright 2020, Wiley. (b) The h-BN-coated LLZTO and uncoated LLZTO. Reproduced with permis- sion[90]. Copyright 2020, American Chemical Society

Figure 10. The Operando XANES studies of SSLBs with bare and LNO-coated NCM811 cathodes during cycling: S K-edge spectra, Ni K-edge spectra, and charge/discharge profiles of (a-c) bare-NCM811- LGPS, (d-f) LNO coated NCM811-LGPS. Reproduced with permi- ssion[106]. Copyright 2020, American Chemical Society

Figure 11. (a) Schematic of in situ XRD investigation. (b) Li2S phase evolution in the bare Li/S and the TG-Li/S battery, demonstrating that Li2S cannot deposit on the metallic Li surface of TG-Li. Reproduced with permission[108]. Copyright 2018, American Chemical Society

Figure 12. In situ NDP measurement. (a) The Li/garnet/CNT asymmet- ric cell and (b) the Li/garnet/Li symmetric cell while cycling. Typical NDP spectra after background calibration at different times (1, 4) and during one plating-stripping cycle (2, 5). (3, 6) 2D projection of NDP spectra collected every 5 min during cycling. Reproduced with permiss- ion[112]. Copyright 2017, American Chemical Society

References 119

[1]	Armand, M.; Tarascon, J.-M. Nature 2008, 451, 652. doi: 10.1038/451652a
[2]	Kang, B.. Ceder, G. Nature 2009, 458, 190. doi: 10.1038/nature07853
[3]	Etacheri, V.; Marom, R.; Elazari, R.; Salitra, G.. Aurbach, D. Energy Environ. Sci. 2011, 4. 3243. doi: 10.1039/c1ee01598b
[4]	Dunn, B.; Kamath, H.; Tarascon, J.-M. Science 2011, 334, 928. doi: 10.1126/science.1212741
[5]	Manthiram, A.; Yu, X. W.; Wang, S. F. Nat. Rev. Mater. 2017, 2, 18.
[6]	Liu, J.; Xu, J. Y.; Lin, Y.; Li, J.; Lai, Y. Q.; Yuan, C. F.; Zhang, J.; Zhu, K. Acta Chim. Sinica 2013, 71, 869. (in Chinese) doi: 10.6023/A13020170
	(刘晋, 徐俊毅, 林月, 李劼, 赖延清, 袁长福, 张锦, 朱凯, 化学学报, 2013, 71, 869.) doi: 10.6023/A13020170
[7]	Cao, D. X.; Sun, X.; Li, Q.; Natan, A.; Xiang, P. Y.; Zhu, H. L. Matter 2020, 2, 1. doi: 10.1016/j.matt.2019.12.003
[8]	Zhang, T.; Yang, Z.; Li, H. L.; Zhuang, Q. C.; Cui, Y. H. Acta Chim. Sinica 2019, 77, 525. (in Chinese) doi: 10.6023/A19010013
	(张桐, 杨梓, 李红亮, 庄全超, 崔艳华, 化学学报, 2019, 77, 525.) doi: 10.6023/A19010013
[9]	Gong, Y.; Chen, Y. Y.; Zhang, Q. H.; Meng, F. Q.; Shi, J. - A.; Liu, X. Y.; Liu, X. Z.; Zhang, J. N.; Wang, H.; Wang, J. Y.; Yu, Q.; Zhang, Z.; Xu, Q.; Xiao, R. J.; Hu, Y. -S.; Gu, L.; Li, H.; Huang, X. J.; Chen, L. Q. Nat. Commun. 2018, 9, 3341. doi: 10.1038/s41467-018-05833-x pmid: 30131492
[10]	Liu, Y. J.; Li, C.; Li, B. J.; Song, H. C.; Cheng, Z.; Chen, M. R.; He, P.. Zhou, H. S. Adv. Energy Mater. 2018, 8, 1702374. doi: 10.1002/aenm.v8.16
[11]	Li, Q. H.; Wang, Y.; Wang, X. L.; Sun, X. R.; Zhang, J. N.; Yu, X. Q.; Li, H. ACS Appl. Mater. Interfaces 2020, 12, 2319. doi: 10.1021/acsami.9b16727
[12]	Du, M. J.; Liao, K. M.; Lu, Q.; Shao, Z. P. Energy Environ. Sci. 2019, 12, 1780. doi: 10.1039/C9EE00515C
[13]	Cheng, Y.; Zhang, L. Q.; Zhang, Q. B.; Li, J.; Tang, Y. F.; Delmas, C.; Zhu, T.; Winter, M.; Wang, M.-S.; Huang, J. Y. Mater. Today 2020, 42, 137. doi: 10.1016/j.mattod.2020.09.003
[14]	Zheng, Y.; Yao, Y. Z.; Ou, J. H.; Li, M.; Luo, D.; Dou, H. Z.; Li, Z. Q; Amine, K.; Yu, A.; Chen, Z. W. Chem. Soc. Rev. 2020, 49, 8790. doi: 10.1039/D0CS00305K
[15]	Li, W. H.; Li, M. S.; Hu, Y. F.; Lu, J.; Lushington, A.; Li, R. Y.; Wu, T. P.; Sham, T.-K.; Sun, X. L. Small Methods 2018, 2, 1700341. doi: 10.1002/smtd.v2.8
[16]	Lin, F.; Liu, Y. J.; Yu, X. Q.; Cheng, L.; Singer, A.; Shpyrko, O. G.; Xin, H. L.; Tamura, N.; Tian, C. X.; Weng, T.-C.; Yang, X.-Q.; Meng, Y. S.; Nordlund, D.; Yang, W. L.; Doeff, M. M. Chem. Rev. 2017, 117, 13123. doi: 10.1021/acs.chemrev.7b00007
[17]	Wang, L. G.; Wang, J. J.; Zuo, P. J. Small Methods 2018, 2, 1700293. doi: 10.1002/smtd.v2.8
[18]	Liu, X.; Gu, L. Small Methods 2018, 2, 1800006. doi: 10.1002/smtd.v2.8
[19]	Yuan, Y. F.; Amine, K.; Lu, J.; Shahbazian-Yassar, R. Nat. Commun. 2017, 8, 15806. doi: 10.1038/ncomms15806
[20]	Zheng, H. M.; Meng, Y. S.; Zhu, Y. M. MRS Bull. 2015, 40, 12. doi: 10.1557/mrs.2014.305
[21]	Yang, Z. Z.; Zhu, Z. Y.; Ma, J.; Xiao, D. D.; Kui, X.; Yao, Y.; Yu, R. C.; Wei, X.; Gu, L.; Hu, Y.-S.; Li, H.; Zhang, X. X. Adv. Energy Mater. 2016, 6, 1600806. doi: 10.1002/aenm.201600806
[22]	Yang, Z. Z.; Ong, P.-V.; He, Y.; Wang, L.; Bowden, M. E.; Xu, W.; Droubay, T. C.; Wang, C. M.; Sushko, P. V.; Du, Y. G. Small 2018, 14, 1803108. doi: 10.1002/smll.v14.52
[23]	Sun, F.; Dong, K.; Osenberg, M.; Hilger, A.; Risse, S.; Lu, Y.; Kamm, P. H.; Klaus, M.; Markötter, H.; García-Moreno, F.; Arlt, T.; Manke, I. J. Mater. Chem. A 2018, 6, 22489. doi: 10.1039/C8TA08821G
[24]	Wu, X. H.; Billaud, J.; Jerjen, I.; Marone, F.; Ishihara, Y.; Adachi, M.; Adachi, Y.; Villevieille, C.; Kato, Y. Adv. Energy Mater. 2019, 9, 1901547. doi: 10.1002/aenm.v9.34
[25]	Haruta, M.; Shiraki, S.; Ohsawa, T.; Suzuki, T.; Kumatani, A.; Takagi, Y.; Shimizu, R.; Hitosugi, T. Solid State Ion. 2016, 285, 118. doi: 10.1016/j.ssi.2015.06.007
[26]	Chen, C. G.; Oudenhoven, J. F. M.; Danilov, D. L.; Vezhlev, E.; Gao, L.; Li, N.; Mulder, F. M.; Eichel, R.-A.; Notten, P. H. L. Adv. Energy Mater. 2018, 8, 1901547.
[27]	Li, Q.; Yi, T. C.; Wang, X. L.; Pan, H. Y.; Quan, B. G.; Liang, T. J.; Guo, X. X.; Yu, X. Q.; Wang, H.; Huang, X. J.; Chen, L. Q.; Li, H. Nano Energy 2019, 63, 1901547.
[28]	Liu, M.; Cheng, Z.; Qian, K.; Verhallen, T.; Wang, C.; Wagemaker, M. Chem. Mater. 2019, 31, 4564. doi: 10.1021/acs.chemmater.9b01325
[29]	Nakayama, M.; Wada, S.; Kuroki, S.; Nogami, M. Energy Environ. Sci. 2010, 3, 1995. doi: 10.1039/c0ee00266f
[30]	He, Y.; Ren, X. D.; Xu, Y. B.; Engelhard, M. H.; Li, X. L.; Xiao, J.; Liu, J.; Zhang, J.-G.; Xu, W.; Wang, C. M. Nat. Nanotechnol. 2019, 14, 1. doi: 10.1038/s41565-018-0355-0
[31]	Zhang, L. Q.; Yang, T. T.; Du, C. C.; Liu, Q. N.; Tang, Y. S.; Zhao, J.; Wang, B. L.; Chen, T. W.; Sun, Y.; Jia, P.; Li, H.; Geng, L.; Chen, J. Z.; Ye, H. J.; Wang, Z. F.; Li, Y. S.; Sun, H. M.; Li, X. M.; Dai, Q. S.; Tang, Y. F.; Peng, Q. M.; Shen, T. D.; Zhang, S. L.; Zhu, T.; Huang, J. Y. Nat. Nanotechnol. 2020, 15, 94. doi: 10.1038/s41565-019-0604-x
[32]	Kuhne, M.; Borrnert, F.; Fecher, S.; Ghorbani-Asl, M.; Biskupek, J.; Samuelis, D.; Krasheninnikov, A. V.; Kaiser, U.; Smet, J. H. Nature 2018, 564, 234. doi: 10.1038/s41586-018-0754-2
[33]	Yan, K.; Lu, Z. D.; Lee, H.-W.; Xiong, F.; Hsu, P.-C.; Li, Y. Z.; Zhao, J.; Chu, S.; Cui, Y. Nat. Energy 2016, 1, 16010. doi: 10.1038/nenergy.2016.10
[34]	Wang, H. S.; Li, Y. Z.; Li, Y. B.; Liu, Y. Y.; Lin, D. C.; Zhu, C.; Chen, G. X.; Yang, A.; Yan, K.; Chen, H.; Zhu, Y. Y.; Li, J.; Xie, J.; Xu, J. W.; Zhang, Z. W.; Vila, R.; Pei, A.; Wang, K. C.; Cui, Y. Nano Lett. 2019, 19, 1326. doi: 10.1021/acs.nanolett.8b04906
[35]	Zhang, S.; Wang, S. F.; Ling, S. G.; Gao, J.; Wu, J. Y.; Xiao, R. J.; Li, H.; Chem, L. Q. Energy Storage Science and Technol. 2014, 3, 376. (in Chinese)
	(张舒, 王少飞, 凌仕刚, 高健, 吴娇杨, 肖睿娟, 李泓, 陈立泉, 储能科学与技术, 2014, 3, 376.)
[36]	Ma, C.; Cheng, Y. Q.; Yin, K.; Luo, J.; Sharafi, A.; Sakamoto, J.; Li, J. C.; More, K. L.; Dudney, N. J.; Chi, M. F. Nano Lett. 2016, 16, 7030. pmid: 27709954
[37]	Wang, Z. Y.; Santhanagopalan, D.; Zhang, W.; Wang, F.; Xin, H. L.; He, K.; Li, J. C.; Dudney, N.; Meng, Y. S. Nano Lett. 2016, 16, 3760. doi: 10.1021/acs.nanolett.6b01119
[38]	Zhu, J. P.; Zhao, J.; Xiang, Y. X.; Lin, M.; Wang, H. M.C.; Zheng, B. Z.; He, H. J.; Wu, Q. H.; Huang, J. Y.; Yang, Y. Chem. Mater. 2020, 32, 4998. doi: 10.1021/acs.chemmater.9b05295
[39]	Lewis, J. A.; Cortes, F. J. Q.; Boebinger, M. G.; Tippens, J.; Marchese, T. S.; Kondekar, N.; Liu, X. M.; Chi, M. F.; McDowell, M. T. ACS Energy Lett. 2019, 4, 591. doi: 10.1021/acsenergylett.9b00093
[40]	Cheng, Q.; Li, A. J.; Li, N.; Li, S.; Zangiabadi, A.; Li, T.-D.; Huang, W. L.; Li, A. C.; Jin, T.; Song, Q. Q.; Xu, W. H.; Ni, N.; Zhai, H. W.; Dontigny, M.; Zaghib, K.; Chuan, X. Y; Su, D.; Yan, K.. Yang, Y. Joule 2019, 3, 1510. doi: 10.1016/j.joule.2019.03.022
[41]	Li, Q. Q.; Liu, H. G.; Yao, Z. P.; Cheng, J. P.; Li, T. H.; Li, Y.; Wolverton, C.; Wu, J. S.; Dravid, V. P. ACS Nano 2016, 10, 8788. doi: 10.1021/acsnano.6b04519
[42]	Fu, M.; Yao, Z. P.; Ma, X.; Dong, H.; Sun, K.; Hwang, S.; Hu, E. Y.; Gan, H.; Yao, Y.; Stach, E. A.; Wolverton, C.; Su, D. Nano Energy 2019, 63, 103882. doi: 10.1016/j.nanoen.2019.103882
[43]	Tang, W.; Chen, Z. X.; Tian, B. B.; Lee, H.-W.; Zhao, X. X.; Fan, X. F.; Fan, Y. C.; Leng, K.; Peng, C. X.; Kim, M.-H.; Li, M.; Lin, M.; Su, J.; Chen, J. Y.; Jeong, H. Y.; Yin, X. S.; Zhang, Q. F.; Zhou, W.; Loh, K. P.; Zheng, G. W. J. Am. Chem. Soc. 2017, 139, 10133. doi: 10.1021/jacs.7b05371 pmid: 28671465
[44]	Nomura, Y.; Yamamoto, K.; Hirayama, T.; Igaki, E.; Saitoh, K. ACS Energy Lett. 2020, 5, 2098. doi: 10.1021/acsenergylett.0c00942
[45]	Shimoyamada, A.; Yamamoto, K.; Yoshida, R.; Kato, T.; Iriyama, Y.; Hirayama, T. Microscopy 2015, 64, 401. doi: 10.1093/jmicro/dfv050 pmid: 26337787
[46]	Yamamoto, K.; Iriyama, Y.; Hirayama, T. Mater. Trans. 2015, 56, 617. doi: 10.2320/matertrans.M2015014
[47]	Nomura, Y.; Yamamoto, K.; Hirayama, T.; Ohkawa, M.; Igaki, E.; Hojo, N.; Saitoh, K. Nano Lett. 2018, 18, 5892. doi: 10.1021/acs.nanolett.8b02587 pmid: 30130410
[48]	Gong, Y.; Zhang, J. N.; Jiang, L. W.; Shi, J.-A.; Zhang, Q. H.; Yang, Z. Z.; Zou, D. L.; Wang, J. Y.; Yu, X. Q.; Xiao, R. J.; Hu, Y.-S.; Gu, L.; Li, H.; Chen, L. Q. J. Am. Chem. Soc. 2017, 139, 4274. doi: 10.1021/jacs.6b13344 pmid: 28274118
[49]	Lan, X. N.; Ye, W. B.; Zheng, H. F.; Cheng, Y.; Zhang, Q. B.; Peng, D.-L.; Wang, M.-S. Nano Energy 2019, 66, 104178. doi: 10.1016/j.nanoen.2019.104178
[50]	Lin, D. C.; Liu, Y. Y.; Liang, Z.; Lee, H.-W.; Sun, J.; Wang, H. T.; Yan, K.; Xie, J.; Cui, Y. Nat. Nanotechnol. 2016, 11, 626. doi: 10.1038/nnano.2016.32
[51]	Liu, S.; Wang, A.; Li, Q.; Wu, J.; Chiou, K.; Huang, J.; Luo, J. Joule 2018, 2, 184. doi: 10.1016/j.joule.2017.11.004
[52]	Ye, W.; Pei, F.; Lan, X.; Cheng, Y.; Fang, X.; Zhang, Q.; Zheng, N.; Peng, D. L.; Wang, M. S. Adv. Energy Mater. 2020, 10, 1902956. doi: 10.1002/aenm.v10.7
[53]	Chen, Y. M.; Wang, Z. Q.; Li, X. Y.; Yao, X. H.; Wang, C.; Li, Y. T.; Xue, W. J.; Yu, D. W.; Kim, S. Y.; Yang, F.; Kushima, A.; Zhang, G. G.; Huang, H. T.; Wu, N.; Mai, Y.-W.; Goodenough, J. B.; Li, J. Nature 2020, 578, 251. doi: 10.1038/s41586-020-1972-y
[54]	Yang, T.; Jia, P.; Liu, Q.; Zhang, L.; Du, C.; Chen, J.; Ye, H.; Li, X.; Li, Y.; Shen, T.; Tang, Y.; Huang, J. Angew. Chem. Int. Ed. 2018, 57, 12750. doi: 10.1002/anie.201807355
[55]	Wang, L. L.; Xie, R. C.; Chen, B. B.; Yu, X. R.; Ma, J.; Li, C.; Hu, Z. W.; Sun, X. W.; Xu, C. J.; Dong, S. M.; Chan, T.-S.; Luo, J.; Cui, G. L.; Chen, L. Q. Nat. Commun. 2020, 11, 5889. doi: 10.1038/s41467-020-19726-5
[56]	Masuda, H.; Ishida, N.; Ogata, Y.; Ito, D.; Fujita, D. Nanoscale 2017, 9, 893. doi: 10.1039/C6NR07971G
[57]	Nomura, Y.; Yamamoto, K.; Hirayama, T.; Ouchi, S.; Igaki, E.; Saitoh, K. Angew. Chem. Int. Ed. 2019, 131, 5346. doi: 10.1002/ange.v131.16
[58]	Wan, J.; Hao, Y.; Shi, Y.; Song, Y. X.; Yan, H. J.; Zheng, J.; Wen, R.; Wan, L. J. Nat. Commun. 2019, 10, 3265. doi: 10.1038/s41467-019-11197-7
[59]	Shi, Y.; Wan, J.; Liu, G. X.; Zuo, T. T.; Song, Y. X.; Liu, B.; Guo, Y. G.; Wen, R.; Wan, L. J. Angew. Chem. Int. Ed. 2020, 59, 18120. doi: 10.1002/anie.v59.41
[60]	Shen, C.; Hu, G. H.; Cheong, L.-Z.; Huang, S. Q.; Zhang, J.-G.. Wang, D. Y. Small Methods 2018, 2, 1700298. doi: 10.1002/smtd.v2.2
[61]	Kalinin, S.; Balke, N.; Jesse, S.; Tselev, A.; Kumar, A.; Arruda, T. M.; Guo, S.; Proksch, R. Mater. Today 2011, 14, 548. doi: 10.1016/S1369-7021(11)70280-2
[62]	Mahankali, K.; Thangavel, N. K.; Arava, L. M. R. Nano Lett. 2019, 19, 5229. doi: 10.1021/acs.nanolett.9b01636 pmid: 31322899
[63]	Wan, J.; Shen, Z. Z.; Wen, R.; Wan, L. J. Sci. Sin. Chim. 2021, 51, 264. (in Chinese) doi: 10.1360/SSC-2020-0195
	(万静, 沈珍珍, 文锐, 万立骏, 中国科学化学, 2021, 51, 264.)
[64]	Shen, Z. Z.; Zhou, C.; Wen, R.; Wan, L. J. J. Am. Chem. Soc. 2020, 142, 16007. doi: 10.1021/jacs.0c07167
[65]	Zhao, W. D.; Song, W. T.; Cheong, L. Z.; Wang, D.Y.; Li, H.; Besenbacher, F.; Huang, F. Q.; Shen, C. Ultramicroscopy 2019, 204, 34. doi: 10.1016/j.ultramic.2019.05.004
[66]	Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J.-M. Nat. Mater. 2011, 11, 19. doi: 10.1038/nmat3191
[67]	Pang, Q.; Liang, X.; Kwok, C. Y.; Nazar, L. F. Nat. Energy 2016, 1, 16132. doi: 10.1038/nenergy.2016.132
[68]	Song, Y. X.; Shi, Y.; Wan, J.; Liu, B.; Wan, L. J.; Wen, R. Adv. Energy Mater. 2020, 10, 2000465. doi: 10.1002/aenm.v10.25
[69]	Wan, J.; Song, Y. X.; Chen, W. P.; Guo, H. J.; Shi, Y.; Guo, Y. J.; Shi, J. L.; Guo, Y. G.; Jia, F. F.; Wang, F. Y.; Wen, R.; Wan, L. J. J. Am. Chem. Soc. 2021, 143, 839. doi: 10.1021/jacs.0c10121
[70]	Guo, H. J.; Wang, H. X.; Guo, Y. J.; Liu, G. X.; Wan, J.; Song, Y. X.; Yang, X. A.; Jia, F. F.; Wang, F. Y.; Guo, Y. G.; Wen, R.; Wan, L. J. J. Am. Chem. Soc. 2020, 142, 20752. doi: 10.1021/jacs.0c09602
[71]	Yulaev, A.; Oleshko, V.; Haney, P.; Liu, J. L.; Qi, Y.; Talin, A. A.; Leite, M. S.; Kolmakov, A. Nano Lett. 2018, 18, 1644. doi: 10.1021/acs.nanolett.7b04518
[72]	Golozar, M.; Hovington, P.; Paolella, A.; Bessette, S.; Lagace, M.; Bouchard, P.; Demers, H.; Gauvin, R.; Zaghib, K. Nano Lett. 2018, 18, 7583. doi: 10.1021/acs.nanolett.8b03148 pmid: 30462516
[73]	Hovington, P.; Lagace, M.; Guerfi, A.; Bouchard, P.; Mauger, Julien, C. M.; Armand, M.; Zaghib, K. Nano Lett. 2015, 15, 2671. doi: 10.1021/acs.nanolett.5b00326 pmid: 25714564
[74]	Marceau, H.; Kim, C.-S.; Paolella, A.; Ladouceur, S.; Lagacé, M.; Chaker, M.; Vijh, A.; Guerfi, A.; Julien, C. M.; Mauger, A.; Armand, M.; Hovington, P.; Zaghib, K. J. Power Sources 2016, 319, 247. doi: 10.1016/j.jpowsour.2016.03.093
[75]	Li, W. H.; Liang, J. W.; Li, M. S; Adair, K. R.; Li, X. N.; Hu, Y. F.; Xiao, Q. F.; Feng, R. F.; Li, R. Y.; Zhang, L.; Lu, S. G.; Huang, H.; Zhao, S. Q.; Sham, T.-K.; Sun, X. L. Chem. Mater. 2020, 32, 7019. doi: 10.1021/acs.chemmater.0c02419
[76]	Zhang, L.; Qian, T.; Zhu, X. Y.; Hu, Z. L.; Wang, M. F.; Zhang, L. Y.; Jiang, T.; Tian, J.-H.. Yan, C. L. Chem. Soc. Rev. 2019, 48, 5432. doi: 10.1039/c9cs00381a pmid: 31647083
[77]	Chen, B. B.; Zhang, H.; Xuan, J.; Offer, G. J.; Wang, H. Z. Adv. Mater. Technol. 2020, 5, 2000555. doi: 10.1002/admt.v5.10
[78]	Song, Y. X.; Shi, Y.; Wan, J.; Lang, S. Y.; Hu, X. C.; Yan, H. J.; Liu, B.; Guo, Y. G.; Wen, R.; Wan, L. J. Energy Environ. Sci. 2019, 12, 2496. doi: 10.1039/C9EE00578A
[79]	Manalastas, W.; Rikarte, J.; Chater, R. J.; Brugge, R.; Aguadero, A.; Buannic, L.; Llordés, A.; Aguesse, F.; Kilner, J. J. Power Sources 2019, 412, 287. doi: 10.1016/j.jpowsour.2018.11.041
[80]	Kazyak, E.; Garcia-Mendez, R.; LePage, W. S.; Sharafi, A.; Davis, A. L.; Sanchez, A. J.; Chen, K.-H.; Haslam, C.; Sakamoto, J.; Dasgupta, N. P. Matter 2020, 2, 1025. doi: 10.1016/j.matt.2020.02.008
[81]	Yan, Y. Y.; Cheng, C.; Zhang, L.; Li, Y. G.; Lu, J. Adv. Energy Mater. 2019, 9, 1900148. doi: 10.1002/aenm.v9.18
[82]	Tippens, J.; Miers, J. C.; Afshar, A.; Lewis, J. A.; Cortes, F. J. Q.; Qiao, H.; Marchese, T. S.; Di Leo, C. V.; Saldana, C.; McDowell, M. T. ACS Energy Lett. 2019, 4, 1475. doi: 10.1021/acsenergylett.9b00816
[83]	Sun, N.; Liu, Q. S.; Cao, Y.; Lou, S. F.; Ge, M. Y.; Xiao, X. H.; Lee, W.-K.; Gao, Y. Z.; Yin, G. P.; Wang, J. J.; Sun, X. L. Angew. Chem. Int. Ed. 2019, 58, 18647. doi: 10.1002/anie.v58.51
[84]	Zhang, J.; Zheng, C.; Li, L. J.; Xia, Y.; Huang, H.; Gan, Y. P.; Liang, C.; He, X. P.; Tao, X. Y.; Zhang, W. K. Adv. Energy Mater. 2019, 10, 1903311. doi: 10.1002/aenm.v10.4
[85]	Zhou, Y. D.; Doerrer, C.; Kasemchainan, J.; Bruce, P. G.; Pasta, M.; Hardwick, L. J. Batteries Supercaps. 2020, 3, 647. doi: 10.1002/batt.v3.7
[86]	Matsuda, Y.; Kuwata, N.; Okawa, T.; Dorai, A.; Kamishima, O.; Kawamura, J. Solid State Ion. 2019, 335, 7. doi: 10.1016/j.ssi.2019.02.010
[87]	Zhao, E.; Nie, K.; Yu, X.; Hu, Y.-S.; Wang, F.; Xiao, J.; Li, H.. Huang, X. Adv. Funct. Mater. 2018, 28, 1707543. doi: 10.1002/adfm.v28.38
[88]	Li, X. L.; Guan, H. L.; Ma, Z. J.; Liang, M.; Song, D. W.; Zhang, H. Z.; Shi, X. X.; Li, C. L.; Jiao, L. F.; Zhang, L. Q. J. Energy Chem. 2020, 48, 195. doi: 10.1016/j.jechem.2020.01.021
[89]	Shen, X.; Zhang, Q.; Ning, T.; Liu, T.; Luo, Y.; He, X.; Luo, Z.. Lu, A. Mater. Today Chem. 2020, 18, 100368.
[90]	Rajendran, S.; Thangavel, N. K.; Mahankali, K.; Arava, L. M. R. ACS Appl. Energy Mater. 2020, 3, 6775. doi: 10.1021/acsaem.0c00905
[91]	Cao, D. X.; Zhang, Y. B.; Nolan, A. M.; Sun, X.; Liu, C.; Sheng, J. Z.; Mo, Y. F.; Wang, Y.; Zhu, H. L. Nano Lett. 2019, 20, 1483. doi: 10.1021/acs.nanolett.9b02678
[92]	Wang, H.; Yu, M.; Wang, Y.; Feng, Z. X.; Wang, Y. Q.; Lü, X. J.; Zhu, J. L.; Ren, Y.; Liang, C. D. J. Power Sources 2018, 401, 111. doi: 10.1016/j.jpowsour.2018.05.037
[93]	Hirose, E.; Niwa, K.; Kataoka, K.; Akimoto, J.; Hasegawa, M. Mater. Res. Bull. 2018, 107, 361. doi: 10.1016/j.materresbull.2018.07.034
[94]	Bak, S.-M.; Shadike, Z.; Lin, R. Q.; Yu, X. Q.; Yang, X. Q. NPG Asia Mater. 2018, 10, 563. doi: 10.1038/s41427-018-0056-z
[95]	Safanama, D.; Sharma, N.; Rao, R. P.; Brand, H. E. A.; Adams, S. J. Mater. Chem. A 2016, 4, 7718. doi: 10.1039/C6TA00402D
[96]	Kazyak, E.; Chen, K.-H.; Wood, K. N.; Davis, A. L.; Thompson, T.; Bielinski, A. R.; Sanchez, A. J.; Wang, X.; Wang, C.; Sakamoto, J.; Dasgupta, N. P. Chem. Mater. 2017, 29, 3785. doi: 10.1021/acs.chemmater.7b00944
[97]	Wu, X. H.; Villevieille, C.; Novak, P.; El Kazzi, M. Phys. Chem. Chem. Phys. 2018, 20, 11123. doi: 10.1039/C8CP01213J
[98]	Akada, K.; Sudayama, T.; Asakura, D.; Kitaura, H.; Nagamura, N.; Horiba, K.; Oshima, M.; Hosono, E.; Harada, Y. J. Electron. Spectrosc. 2019, 233, 64. doi: 10.1016/j.elspec.2019.03.006
[99]	Endo, R.; Ohnishi, T.; Takada, K.; Masuda, T. J. Phys. Chem. Lett. 2020, 11, 6649. doi: 10.1021/acs.jpclett.0c01906
[100]	Wenzel, S.; Weber, D. A.; Leichtweiss, T.; Busche, M. R.; Sann, J.; Janek, J. Solid State Ion. 2016, 286, 24. doi: 10.1016/j.ssi.2015.11.034
[101]	Wood, K. N.; Steirer, K. X.; Hafner, S. E.; Ban, C.; Santhanagopalan, S.; Lee, S.-H.; Teeter, G. Nat. Commun. 2018, 9, 2490. doi: 10.1038/s41467-018-04762-z
[102]	Wenzel, S.; Randau, S.; Leichtweiß, T.; Weber, D. A.; Sann, J.; Zeier, W. G.; Janek, J. Chem. Mater. 2016, 28, 2400. doi: 10.1021/acs.chemmater.6b00610
[103]	Zhang, Z. H.; Chen, S. J.; Yang, J.; Wang, J. Y.; Yao, L. L.; Yao, X. Y.; Cui, P.; Xu, X. X. ACS Appl. Mater. Interfaces 2018, 10, 2556. doi: 10.1021/acsami.7b16176
[104]	Vardar, G.; Bowman, W. J.; Lu, Q. Y.; Wang, J. Y.; Chater, R. J.; Aguadero, A.; Seibert, R.; Terry, J.; Hunt, A.; Waluyo, I.; Fong, D. D.; Jarry, A.; Crumlin, E. J.; Hellstrom, S. L.; Chiang, Y.-M.; Yildiz, B. Chem. Mater. 2018, 30, 6259. doi: 10.1021/acs.chemmater.8b01713
[105]	Adair, K. R.; Zhao, C. T.; Banis, M. N.; Zhao, Y.; Li, R. Y.; Cai, M.; Sun, X. L. Angew. Chem. Int. Ed. 2019, 58, 15797. doi: 10.1002/anie.v58.44
[106]	Li, X.; Ren, Z. H.; Norouzi Banis, M.; Deng, S. X.; Zhao, Y.; Sun, Q.; Wang, C. H.; Yang, X. F.; Li, W. H.; Liang, J. W.; Li, X. N.; Sun, Y. P.; Adair, K.; Li, R. Y.; Hu, Y. F.; Sham, T.-K.; Huang, H.; Zhang, L.; Lu, S. G.; Luo, J.; Sun, X. L. ACS Energy Lett. 2019, 4, 2480. doi: 10.1021/acsenergylett.9b01676
[107]	Wang, C. H.; Li, X.; Zhao, Y.; Banis, M. N.; Liang, J. W.; Li, X. N.; Sun, Y. P.; Adair, K. R.; Sun, Q.; Liu, Y. L.; Zhao, F. P.; Deng, S. X.; Lin, X. T.; Li, R. Y.; Hu, Y. F.; Sham, T.-K.; Huang, H.; Zhang, L.; Yang, R.; Lu, S.G.; Sun, X. L. Small Methods 2019, 3, 1900261. doi: 10.1002/smtd.v3.10
[108]	Liu, J.; Qian, T.; Wang, M. F.; Zhou, J. Q.; Xu, N.; Yan, C. L. Nano Lett. 2018, 18, 4598. doi: 10.1021/acs.nanolett.8b01882
[109]	Robinson, J. P.; Kichambare, P. D.; Deiner, J. L.; Miller, R.; Rottmayer, M. A.; Koenig, G. M. J. Am. Ceram. Soc. 2018, 101, 1087. doi: 10.1111/jace.2018.101.issue-3
[110]	Han, Q. Y.; Wang, S. Q.; Jiang, Z. Y.; Hu, X. C.; Wang, H. H. ACS Appl. Mater. Interfaces 2020, 12, 20514. doi: 10.1021/acsami.0c03430
[111]	Han, F. D.; Westover, A. S.; Yue, J.; Fan, X. L.; Wang, F.; Chi, M. F.; Leonard, D. N.; Dudney, N. J.; Wang, H.; Wang, C. S. Nat. Energy 2019, 4, 187.
[112]	Wang, C. W.; Gong, Y. H.; Dai, J. Q.; Zhang, L.; Xie, H.; Pastel, G.; Liu, B. Y.; Wachsman, E.; Wang, H.; Hu, L. B. J. Am. Chem. Soc. 2017, 139, 14257. doi: 10.1021/jacs.7b07904
[113]	Ping, W. W.; Wang, C. W.; Lin, Z. W.; Hitz, E.; Yang, C. P.; Wang, H.; Hu, L. B. Adv. Energy Mater. 2020, 10, 2000702. doi: 10.1002/aenm.v10.25
[114]	Xu, G. -L.; Sun, H.; Luo, C.; Estevez, L.; Zhuang, M. H.; Gao, H.; Amine, R.; Wang, H.; Zhang, X. Y.; Sun, C.-J.; Liu, Y. Z.; Ren, Y.; Heald, S. M.; Wang, C. S.; Chen, Z. H.; Amine, K. Adv. Energy Mater. 2019, 9, 1802235. doi: 10.1002/aenm.v9.2
[115]	Mohammadi, M.; Jerschow, A. J Magn Reson. 2019, 308, 106600. doi: 10.1016/j.jmr.2019.106600
[116]	Romanenko, K.; Jin, L.; Howlett, P.; Forsyth, M. Chem. Mater. 2016, 28, 2844. doi: 10.1021/acs.chemmater.6b00797
[117]	Kim, S. H.; Kim, K.; Choi, H.; Im, D.; Heo, S.; Choi, H. S. J. Mater. Chem. A 2019, 7, 13650. doi: 10.1039/C9TA02614B
[118]	Metwalli, E.; Kaeppel, M. V.; Schaper, S. J.; Kriele, A.; Gilles, R.; Raftopoulos, K. N.; Müller-Buschbaum, P. ACS Appl. Energy Mater. 2018, 1, 666. doi: 10.1021/acsaem.7b00173
[119]	Möhl, G. E.; Metwalli, E.; Müller-Buschbaum, P. ACS Energy Lett. 2018, 3, 1525. doi: 10.1021/acsenergylett.8b00763

固态锂电池电极过程的原位研究进展

In Situ/Operando Advances of Electrode Processes in Solid-state Lithium Batteries

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 14

References 119

Related Articles 3

Recommended Articles

Metrics

Comments

[1]	JIANG Jun, ZHANG Jun-Xi, LU Jin-Liang, QIAN Sheng-Jie, WU Yong-Cheng, WANG Kun, QU Wen-Jun. Electrochemical Behavior of the Rebar during Re-alkalization Treatment [J]. Acta Chimica Sinica, 2011, 69(20): 2347-2352.
[2]	TAO Mo-Gao, LI Jie, ZHANG Zhong-Ru, GAO Jun, WANG Zhou-Cheng, YANG Yong. Electrochemical Behavior of Vinyl Ethylene Sulfite as an Electrolyte Film-forming Additive in Lithium Ion Batteries [J]. Acta Chimica Sinica, 2009, 67(22): 2531-2535.
[3]	WU ZHIBIN;ZHANG ZUXUN. Investigation on linear sweep voltammetry II: The theory of catalytic current at ultramicrodisk electrode [J]. Acta Chimica Sinica, 1992, 50(3): 274-280.