Light-Responsible Room-Temperature Phosphorescence Materials Based on Diarylethene★

doi:10.6023/A23030077

Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (5): 445-449.DOI: 10.6023/A23030077 Previous Articles Next Articles

Special Issue: 庆祝《化学学报》创刊90周年合辑

Article

基于二芳基乙烯的光响应型室温磷光材料^★

刘懿玮, 马良伟, 王巧纯, 马骧^*()

结构可控先进功能材料及其制备教育部重点实验室费林加诺贝尔奖科学家联合研究中心材料生物学与动态化学前沿科学中心华东理工大学化学与分子工程学院上海 200237

投稿日期:2023-03-10 发布日期:2023-04-10
作者简介:
^★ 庆祝《化学学报》创刊90周年.
基金资助:
国家自然科学基金项目(21788102); 国家自然科学基金项目(22125803); 国家自然科学基金项目(22020102006); 上海市科技重大专项(2018SHZDZX03); 上海市优秀学术带头人项目(20XD1421300); 中央高校基本科研专项基金; 中国博士后创新人才支持计划(BX20220106); 中国博士后科学基金面上项目(2022M721140)

Light-Responsible Room-Temperature Phosphorescence Materials Based on Diarylethene^★

Liu Yiwei, Ma Liangwei, Wang Qiaochun, Ma Xiang()

Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China

Received:2023-03-10 Published:2023-04-10
Contact: *E-mail: maxiang@ecust.edu.cn
About author:
^★Dedicated to the 90th anniversary of Acta Chimica Sinica
Supported by:
National Natural Science Foundation of China(21788102); National Natural Science Foundation of China(22125803); National Natural Science Foundation of China(22020102006); Shanghai Municipal Science and Technology Major Project(2018SHZDZX03); Program of Shanghai Academic/Technology Research Leader(20XD1421300); Fundamental Research Funds for the Central Universities; China National Postdoctoral Program for Innovative Talents(BX20220106); China Postdoctoral Science Foundation(2022M721140)

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Abstract

Photochromic molecules show great potential in biological imaging, logic gates, super-resolution imaging and other fields due to the sensitivity, accuracy and penetrability of light. By utilizing their variations on physical properties upon light irradiation, the fluorescence signal of photochromic dyes can be turned on or off accurately by specific wavelength. As an important luminescent dye, organic room-temperature phosphorescence (RTP) materials have attracted great research interest of scientists by the triplet state radiation process, and have potential in sensing, anticounterfeiting, photo-dynamic therapy, and so forth. In this work, we combine the phosphorescence and photochromic properties together by connecting a classic photochromic dye (bithienylethene) with an efficient phosphor (thiochroman-4-one) via sp² and sp³ linker (BTE1oand BTE2o). These compounds show typical photochromic phenomenon in solution and polymer matrix and have good fatigue resistance. During the irradiation, a clear isosbestic point can be observed, indicating the quantified transition between two isomers. The emission quenching of derivatives is considered as the radiative energy transfer between fluorescent open form and non-fluorescent closed form. It’s interesting that the fluorescence lifetime of BTE1oand BTE2oincreases after ultraviolet (UV) irradiation, which rules out the possibility of non-radiative energy transfer mechanism of the fluorescence quenching phenomena. In the poly(vinyl alcohol) (PVA) matrix, these compounds show decent RTP emission and millisecond level lifetime. And the RTP emission can also be reversibly turned “ON” or “OFF” via irradiation of different wavelengths. It’s very interesting that the phosphorescence lifetime also increases (from 16.1 to 19.4 ms) with the irradiation of UV light, which is identified with the variation of fluorescence lifetime in solution and PVA matrix. The increase of lifetime can rule out the non-radiative energy transfer mechanism for the phosphorescence quenching phenomena. Considering the fluorescence quenching phenomena in tetrahydrofuran (THF) solution, the fluorescence and phosphorescence quenching in PVA matrix should also be attributed to the form conversion and the radiative energy transfer process between open and closed isomers.

Key words: photochromic, room-temperature, phosphorescence, photoresponsive, energy transfer

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Liu Yiwei, Ma Liangwei, Wang Qiaochun, Ma Xiang. Light-Responsible Room-Temperature Phosphorescence Materials Based on Diarylethene^★[J]. Acta Chimica Sinica, 2023, 81(5): 445-449.

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Fig. & Tab. 3

Figure 1. Schematic diagram of design principle and working mechanism of the light-responsive RTP system

Figure 2. Absorption, fluorescence and excitation spectra of BTE1o (a) and BTE2o (e) before UV light irradiation. Variation of the absorption (b, f), fluorescence (c, g) and lifetime decay (d, h) spectra of BTE1o (up) and BTE2o (down) under light irradiation (365 nm light for BTE1o and 405 nm light for BTE2o); inset: photograph of the THF solution of BTE1o or BTE2o under daylight or 365 nm light. Concentration: 1.0×10-5 mol/L, λex=365 nm

Figure 3. Variation of the absorption (a, e), fluorescence (b, f), phosphorescence (c, g) and lifetime decay of phosphorescence (d, h) spectra of BTE1o@PVA (up) and BTE2o@PVA (down) in PVA matrix (0.3% (w)), λex=365 nm

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基于二芳基乙烯的光响应型室温磷光材料^★

Light-Responsible Room-Temperature Phosphorescence Materials Based on Diarylethene^★

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基于二芳基乙烯的光响应型室温磷光材料★

Light-Responsible Room-Temperature Phosphorescence Materials Based on Diarylethene★

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PDF

Supporting Info.

Knowledge

Abstract

Cite this article

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Fig. & Tab. 3

References 49

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基于二芳基乙烯的光响应型室温磷光材料^★

Light-Responsible Room-Temperature Phosphorescence Materials Based on Diarylethene^★