Acta Chimica Sinica ›› 1955, Vol. 21 ›› Issue (2): 101-102.     Next Articles

9:10-α-八氢萘酮的合成

赵华明   

  1. 四川大学化学系
  • 投稿日期:1954-06-23 发布日期:2013-06-04

SYNTHESIS OF △9:10-α-OCTALONE

CHAO HWA-MING   

  1. Department of Chemistry, Szechwan University
  • Received:1954-06-23 Published:2013-06-04

γ-(△1-Cyclohexenyl)-y-ketobutyric cinic anhydride on cyclohexene with acid was prepared in an experiment by action of sucaluminium chloride as catalyst. Meanwhile other catalysts of the Lewis acid type, such as ferric chloride and stannic chloride, were also tried, but the results were not satisfactory. In reducing γ-hyclohexenyl)-γ-ketdbutyric acid to γ-(△1-cyclohexenyl).butyric acid, both Wolff-Kishner's method and Huang Minlon's modification were experimentally employed, the result being unexpectedly in favor of the former.