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Acta Chimica Sinica ›› 1955, Vol. 21 ›› Issue (2): 132-141. Previous Articles     Next Articles

金微素的化学Ⅰ.金微素及其衍化物的氢解和芳构化

黄耀曾, 丁宏勋, 丁维钰, 盛怀禹, 涂通源, 黄敬坚, 徐元耀, 汪猷   

  1. 中国科学院有机化学研究所
  • 投稿日期:1955-01-03 发布日期:2013-06-04

STUDIES ON THE CHEMISTRY OF AUREOMYCIN I. HYDROGENOLYSIS AND AROMATIZATION OF AUREOMYCIN AND ITS DERIVATIVES

HUANG YAO-TSENG(YAO-TSENG HUANG), TING HUNG-SHIUN(HUNG-SHIUN TINC), TING WEI-YI, SHENG HAI-YU, TU TUNG-YUAN, HUANG JING-JAIN, HSU YUEN-YAO, WANG YU(YU WANG)   

  1. Institute of Organic Chemistry, Academia Sinica
  • Received:1955-01-03 Published:2013-06-04

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Aureomycin (Ⅰ) on reduction with zinc-acetic acid gives desdimethylaminoaureomycin (Ⅱ) under mild conditions and desdimethylaminodesoxyaureomycin (Ⅲ) under more drastic conditions. Ⅱ can }be converted into Ⅲ-by further reductictfi.