Acta Chimica Sinica ›› 1955, Vol. 21 ›› Issue (3): 332-335. Previous Articles    

中国鸟头之研究紫草鸟中的植物硷

朱任宏   

  1. 中国科学院药物研究所 上海
  • 投稿日期:1955-06-22 发布日期:2013-06-04

AN ALKALOID OF CHINESE ACONITUM, A. DELAVAYI FRENCH

CHU JEN-HUNG   

  1. Institute of Materia Medica,Academia Sinica,Shanghai
  • Received:1955-06-22 Published:2013-06-04

A new alkaloid was obtained in 0.43% yield from the stem leaves of Chinese Aconitum, identified as A, delavaYi French.It is provisionally named delavaconitine, having the molcular formula, C28 H39O5N·H2O, m.p.59-64°, [α]D17=-9.56°(ethanol, C=0.7%).1"he following crystalline salts have been prepared:(1) nitrate, C28 H39O5N·HNO3·H2O, lusterous fine needles, m.p.154°;(2) perchlorate,C28 H39O5N·HClO4,cluster of prisms, m.p.241°;(3) picrolonate, H39O5N·C10H8N4O5,yellow prisms, m.p.218°;(4)chloroaurate, H39O5N·HAuCl4, golden yellowish prismatic needles, m.p.215°.