Acta Chimica Sinica ›› 1958, Vol. 24 ›› Issue (6): 407-412. Previous Articles     Next Articles

4, 5-二羟基荧光黄用作分析试剂Ⅰ.——用作铅的分析试剂

田冰式, 王夔   

  1. 北京医学院化学教研组
  • 投稿日期:1958-01-23 发布日期:2013-06-03

GALLEIN AS ANALYTICAL REAGENT Ⅰ. ——LEAD GALLEINATE, ITS COMPOSITION AND ANALYICAL APPLICATIONS

T'IEN PING-SHIH, WANG K'UEI   

  1. Department of Chemistry, Peking Medical College
  • Received:1958-01-23 Published:2013-06-03

(1) Gallein forms a blue coloration or precipitate with load ions.Sensitivity:0.2γ(1:5, 000, 000).Cu, Ce, Sb and Sn(Ⅱ, Ⅳ) interfere.(2) The composition of lead galleinate was determined by means of hetercmetric titration method and elope ratio method.The ratio of reagent to lead in the compound formed in alcohol medium was found to he 2:3, while that in aqueous.medium(pH 8), 1:1.