Acta Chimica Sinica ›› 1959, Vol. 25 ›› Issue (1): 1-9,27,28,29,30.     Next Articles

酯化反应的氢离子催化机构Ⅰ.单元酸与单元醇的酯化反应动力学

唐敖庆1, 岳国粹1, 丁开爽1, 朗佩珍2, 赵成大2   

  1. 1. 中国科学院应用化学研究所;
    2. 东北师范大学化学系
  • 投稿日期:1957-09-20 发布日期:2013-06-03

MECHANISM OF HYDROGEN-ION CATALYSIS IN ESTERIFICATION.——Ⅰ.STUDIES ON THE KINETICS OF ESTERIFICATION REACTIONS BETWEEN MONOBASIC ACIDS AND MONOHYDRIC ALCOHOLS.

TANG Au-CHIN1, YAO KUO-SUI1, TING KAI-SHA1, LANG PEI-CHEN2, CHAO CHENG-TA2   

  1. Institute of Applied Chemistry, Academia Sinica
  • Received:1957-09-20 Published:2013-06-03

Altliough esterification reaci,ion hetweeu monobasic acids and monohydric alcculs is a well-known chemical reaction, on which various au bhors, such as Golclschmidt, Hinslielwood, Flory and others, have done much work, but the mechanism of estexification and the or Mcr of the reaction in the absence or presenace of a foreign acid remain unclarified. For this purpose we have studied the kinetics of esterification reactions laetween lauric acid and normal octyl alcohol with eqni- or non-equimolar quantity ratios in the abseence or presence of a foreign acid at different temperatures.