Acta Chimica Sinica ›› 1959, Vol. 25 ›› Issue (1): 73-80. Previous Articles    

脂肪酸钠盐对正戊酸在水中溶度的影响

杨文治, 胡瑶村, 宋果男, 黄子卿, 雷鸿毅   

  1. 北京大学化学系
  • 投稿日期:1958-11-24 发布日期:2013-06-03

THE SOLUBILITIES OF n-VALERIC ACID IN AQUEOUS SALT SOLUTIONS OF SODIUM SALTS OF PATTY ACIDS

YANG WEN-CHEH, HU YAO-CHUN, SUNG KUO-NAN, HUANG TZU-CHING, LEI HUNG-YI   

  1. Department of Chemistry, Peking University
  • Received:1958-11-24 Published:2013-06-03

Huang and Yang[1] studied the effect of five cobalt ammtnes on the solubilities of n-valeric acid in water. These salts salt out the acid, and the amount of salting-out increases with the increase of the charge of the canon. Later, Li and Huang[2] studied the activity coefficients of n-phthalene in seven salts (sodium formats to sodium n-heptylate) of fatty acids and found with the increase of number of carbon atoms in the salts, the salting-ont, of n-phthalene decreases, changes into salting-in, which then continues to increase. But the same five aalt.s (sodium forznate to sodium n-valernte) prodnce an irregnlnr effect of salting-in of caproic acid[3].