Acta Chimica Sinica ›› 1963, Vol. 29 ›› Issue (2): 90-94. Previous Articles     Next Articles

Меншуткин反应的研究Ⅱ.喹啉-碘甲烷在若干脂肪醇中的反应动力学

張工, 雷一鳴, 鍾孔芳, 何淡雲, 孙承諤   

  1. 北京大学化学系
  • 投稿日期:1962-06-17 发布日期:2013-06-03

STUDIES ON THE MENSHUTKIN REACTION Ⅱ. THE KINETICS OF THE REACTION OF QUINOLINE-METHYL IODIDE IN SOME ALIPHATIC ALCOHOLS

CHANG KWUNG, LEI YI-MING, CHUNG KUNG-FANG, HO TAN-YUN, SUN CHENG-E   

  1. Chemistry Department, Peking University
  • Received:1962-06-17 Published:2013-06-03

The specific reaction rates of the bimolecular reaction of quinoline with methyl iodide in some aliphatic alcohols (C3-C3) have been determined at various temperatures (55-800) and found to range between 2.85·10-3-19.2·10-3l/mole·min.The activation energies range between 17.0-19.0 kcal/mole.The specific rate constant of the reaction has been shown to decrease with increase of the number of the carbon atoms of the alcohols, but the activation energy increases slightly.The specific rate constants for the isomeric alcohols are nearly identical.