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Acta Chimica Sinica ›› 1965, Vol. 31 ›› Issue (2): 111-117. Previous Articles     Next Articles

硼氮六环的化学——Ⅰ.B-三氯代-N-三对溴苯基硼氮六环的Grignard反应

曾繁杰, 蒋丽金   

  1. 中国科学院化学研究所
  • 投稿日期:1964-04-01 发布日期:2013-06-03

THE CHEMISTRY OF BORAZOLES Ⅰ. THE GRIGNARD REACTIONS OF B-TRICHLORO-NTRIPARABROMOPHENYLBORAZOLE

TSENG FAN-CHIEH, CHIANG LI-CHIN   

  1. Institute of Chemistry, Academia Sinica, Peking
  • Received:1964-04-01 Published:2013-06-03

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In toluene,the π-molecular orbital complex(ClB·N·C6H4·Br-P)3·1/26H5CH3 was prepared from boron trichloride and p-bromoaniline by one-step reaction.In chlorobenzene,only(ClB·N·C6H4·Br-P)3 was obtained.A tentative explanation was suggested.