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Acta Chimica Sinica ›› 1976, Vol. 34 ›› Issue (2): 149-152. Previous Articles
前列腺素合成组
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THE PROSTAGLANDIN SYNTHESIS GROUP Shanghai
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dl-Prostaglandin F2α(Ⅹ) was synthesized from cyclopentadiene via a ten-step process.dl-Diol(Ⅱa) was epoxidized sterospecifically by peraoids to the dl-epozide(Ⅲa),the structure of whioh was established by oxidation to the known compound (ⅩⅤ).However,the diacetate(Ⅱb) reaoted with peracids to give a 1:1 mixture of cis-syn-cis and cis-anti-cis dl-isomers (Ⅲb) and (ⅩⅡ).
THE PROSTAGLANDIN SYNTHESIS GROUP Shanghai. THE SYNTHESES OF dl-PROSTAGLANDIN F2a[J]. Acta Chimica Sinica, 1976, 34(2): 149-152.
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